tests for anions and cations Flashcards
test for halide ions using silver nitrate solution needs what
- dilute nitric acid (HNO3)
- silver nitrate solution (AgNO3 )
why can’t you use hydrochloric acid when testing for halide ions
- you’d be adding chloride ions
why when testing for halide ions does nitric acid have to be added first?
- to get rid of any carbonate ions - they produce a pale precipitate with silver nitrate and might confuse results
what does a chloride ion make when silver nitrate is added
- it gives a white precipitate of silver chloride
- Ag+ + Cl- → AgCl (s)
what does a bromide ion make when silver nitrate is added
- a bromide ion gives a cream precipitate of silver bromide
- Ag+ + Br- → AgBr (s)
what does a iodide ion make when silver nitrate is added
- an iodide gives a yellow precipitate of silver iodide
- Ag+ + I- → AgI (s)
how to test for carbonates using hydrochloric acid
- to test for carbonate ions
- add some barium chloride solution
- if there are carbonate ions a white precipitate of barium carbonate produced
- then add dilute hydrochloric acid
- if there are carbonate ions the mixture will fizz producing carbon dioxide
- if gas is collected and pass through limewater the limewater should turn cloudy
- once it has all reacted a colorless solution is formed containing Ba2+ ions
what is the formula for carbonates
- BaCO3+2H → Ba2+ + CO2 +H2O
how to test for sulphate ions
- add barium chloride solution
- sulphate ions = white precipitate of barium sulphate
- add dilute hydrochloric acid
- barium sulphate wont react with hcl so white precipitate will not dissolve so
- sulfate ions not carbonate ions
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what is the formula for testing sulfate ions
Ba+2+SO42-→BaSO4
How can we test for metal ions?
- Pit substance in flame
- see what colors flame goes
Describe the practical for finding metal ions
- Clean nichrome wire look with hcl then rinse in deionised water
- dip wire loop in metal compound
- put Wire loop in blue flame of Bunsen burner
- see what color it goes
Explain the test for metal ions with sodium hydroxide
- Add a few drops of sodium hydroxide solution to the unknown compound
- if a hydroxide precipitate forms the color can be used to se what metal ion was in the compound
What colour flame does Lithium, Li+ give
- Brick red
What colour flame does Sodium, Na+ give
Yellow