tests for anions and cations Flashcards

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1
Q

test for halide ions using silver nitrate solution needs what

A
  • dilute nitric acid (HNO3)
  • silver nitrate solution (AgNO3 )
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2
Q

why can’t you use hydrochloric acid when testing for halide ions

A
  • you’d be adding chloride ions
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3
Q

why when testing for halide ions does nitric acid have to be added first?

A
  • to get rid of any carbonate ions - they produce a pale precipitate with silver nitrate and might confuse results
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4
Q

what does a chloride ion make when silver nitrate is added

A
  • it gives a white precipitate of silver chloride
  • Ag+ + Cl- → AgCl (s)
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5
Q

what does a bromide ion make when silver nitrate is added

A
  • a bromide ion gives a cream precipitate of silver bromide
  • Ag+ + Br- → AgBr (s)
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6
Q

what does a iodide ion make when silver nitrate is added

A
  • an iodide gives a yellow precipitate of silver iodide
  • Ag+ + I- → AgI (s)
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7
Q

how to test for carbonates using hydrochloric acid

A
  • to test for carbonate ions
  1. add some barium chloride solution
  2. if there are carbonate ions a white precipitate of barium carbonate produced
  3. then add dilute hydrochloric acid
  4. if there are carbonate ions the mixture will fizz producing carbon dioxide
  5. if gas is collected and pass through limewater the limewater should turn cloudy
  6. once it has all reacted a colorless solution is formed containing Ba2+ ions
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8
Q

what is the formula for carbonates

A
  • BaCO3+2H → Ba2+ + CO2 +H2O
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9
Q

how to test for sulphate ions

A
  1. add barium chloride solution
  2. sulphate ions = white precipitate of barium sulphate
  3. add dilute hydrochloric acid
  4. barium sulphate wont react with hcl so white precipitate will not dissolve so
  5. sulfate ions not carbonate ions

*

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10
Q

what is the formula for testing sulfate ions

A

Ba+2+SO42-→BaSO4

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11
Q

How can we test for metal ions?

A
  1. Pit substance in flame
  2. see what colors flame goes
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12
Q

Describe the practical for finding metal ions

A
  1. Clean nichrome wire look with hcl then rinse in deionised water
  2. dip wire loop in metal compound
  3. put Wire loop in blue flame of Bunsen burner
  4. see what color it goes
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13
Q

Explain the test for metal ions with sodium hydroxide

A
  1. Add a few drops of sodium hydroxide solution to the unknown compound
  2. if a hydroxide precipitate forms the color can be used to se what metal ion was in the compound
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14
Q

What colour flame does Lithium, Li+ give

A
  • Brick red
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15
Q

What colour flame does Sodium, Na+ give

A

Yellow

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16
Q

What colou flame does Potassium, K+ give

A

Lilac

17
Q

What coloured flame does Calcium, Ca2+ give

A

Orange-red

18
Q

What coloured flame does Barium, Ba2+give

A

Green

19
Q

What coloured flame does Copper, Cu2+ give

A