Test for ions Flashcards
How do you test for Magnesium ions?
excess NaOH - White ppt
Ca2+
excess NaOH - Slight white ppt
Ba2+
excess sulfuric acid - white ppt
Write the equation for the test for Mg2+. Ca2+. Ba2+
NH4+
Warm with NaOH and test gas with damp red litmus - turns blue
Write the equation for the test for NH4+
Ag+
Sodium chloride - white precipitate
Write the half equation for the test for Ag+
H+
Soluble carbonate or hydrogencarbonate - effervescence
Write the equation for the test for H+
CO32-
hydrochloric acid = effervescent
What is the equation for the test for carbonate ions
OH-
MgCl2 - white ppt OR NH4Cl and warm - test gas with damp red litmus - turns blue
What is the equation for the test of OH-
What is the reaction between halide ions and silver nitrates used for?
to discover which halide ion is present
Describe how to carry out the reaction of halide ions with silver nitrate and how to carry out the subsequent tests used to distinguish them further
make the test solution by adding nitric acid to the sample and then adding silver nitrate solution dropwise
Subsequent tests: add some dilute ammonia solution dropwise until it is excess. After add concentrated ammonia solution dropwise until it is excess
Describe the results seen when halide ions react with silver nitrate
Fluorides produce no precipitate
Chlorides produce a white precipitate
Bromides produce cream precipitate
Iodides produce a pale yellow precipitate
What is the test for sulfate ions?
adding barium chloride acidified with hydrochloric acid/ nitric acid to a solution containing sulfate ions, then a white precipitate of barium sulfate is formed
Describe the results seen when halide ions react with dilute ammonia and concentrated ammonia
Florine= nothing
Chlorine = white precipitate dissolves, goes clear (soluble) in both
Bromide= insoluble in one, cream precipitate dissolves in concentrated ammonia (goes clear)
Iodine= insoluble in both
Write the ionic equation for the test for sulfate ions
Write the ionic equation for when there are carbonates present during a test for sulfates
2H+ CO32- → H2O +CO2