T4.1 Spivak Flashcards
1
Q
Benzene –> Sulfa group Benzene
A
H2SO4 (SO3)
2
Q
Sulfa benzene –> Benzene
A
H2O / Heat
3
Q
Benzene –> ChloroBenzene
A
AlCl3 + Br2 / Cl2
4
Q
Benzene –> Acyl benzene
A
AlCl3 + Acid chloride
5
Q
Benzene –> Benzene with R chain
A
AlCl3 + R Alkyl halide
6
Q
Acyl benzene –> R group benzene
A
Reduce using Zn and HCl
7
Q
Nitrobenzene –> Amino benzene
A
Sn/ HCl
8
Q
Amino benzene to Diazonoum salt
A
NaNO2 / HCl (make NO nitrosonium ion first)
9
Q
Diazonium benzene salt –> Benzyl halide
A
CuCl or CuBr
10
Q
Diazonium benzene –> Benzonitrile
A
CuCN
11
Q
Diazonium benzene –> Iodobenzene
A
KI
12
Q
Diazonium benzene –> Fluorobenzene
A
HBF4
13
Q
Diazonium benzene –> Benzene
A
H3PO2
14
Q
Diazonium benzene –> Phenol
A
H2O / warm
15
Q
R chain benzene –> CA
A
KMnO4
