systematic carbon chemistry Flashcards
How are compound with single C-C bonds described?
saturated
How are compounds with double C=C bonds described
unsaturated
What can unsaturated molecules take part in?
addition reactions, e.g. decolourisation of bromine solution
What are isomers?
compounds with same molecular formula but different structures, different physical properties.
What can be used to predict the solubility, boiling point or volatility of a molecule?
presence of -NH, -OH, -FH, hydrogen bonding
spatial arrangement of polar bonds, pd-pd interactions
molecular size, LDF strength
polarities of solvent and solute, like dissolves like
What contain only single C-C bonds and H’s, saturated
Alkanes
Min. 3 C in circular shape, single C-C bonds, saturated
Cycloalkanes
What contain one C=C double bond, min. 2 C, unsaturated
Alkenes
What could be used as a solvent for alkanes, cycloalkanes and alkenes?
Hexane as they are hydrocarbons therefore non-polar
Step by step process for systematic naming?
- Identify longest carbon chain and name accordingly.
- With alkanes or any molecule with a functional group (e.g. -OH), number so that the functional group is as low as possible.
- Name branches accordingly and number.
- Use di- tr- if more than one double bond/functional group
What compounds can undergo addition reactions?
Compounds containing double bonds.
Example of an addition reaction.
bromine solution can distinguish between unsaturated and saturated compounds by addition reactions. Bromine can be replaced with other halogens as well as hydrogen halides.