surfactants Flashcards
what is interface?
boundary between 2 phases
what is a surface?
boundary between 2 phases when 1 is a gas
what is surface energy?
potential energy per unit surface area
what lowers a molecules surface energy?
intermolecular bonds
what is surface tension?
‘film’ on surface that resists puncture
energy required to expand the surface of a liquid by a unit area
2 techniques to measure surface tension?
ring - cylinder in and out
plate - dip something in and out
what does contact angle indicate?
indicates surface wettability
what does a larger contact angle mean?
less wettability
what is wettability?
tendency of liquid to adhere to a solid surface
how do surfactants work?
reduce surface tension by reducing bonding between water
how are micelles formed?
when a liquid is saturated with a surfactant the excess sinks below surface
what is CMC?
critical micelle concentration
minimum conc. of surfactant when micelles form
what is Traube’s rule?
molar conc. of surfactant needed to achieve a certain surface tension decreases by around 3 fold with each CH2 unit in homologous series