Surface Chemistry Flashcards

1
Q

What are the bonds used in Physiosorption and Chemisorption respectively?

A

Van Der Wall bonds are used in Physiosorption and Strong Chemical Bonds are used in Chemisorption

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2
Q

What is adsorption Isobar?

A

Adsorption Isobar is a plot of extent of adsorption(x/m) Vs Temperature at constant pressure

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3
Q

What is adsorption Isotherm?

A

Adsorption Isotherm is the plot of extent of adsorption(x/m) vs Pressure at constant temperature. ‘x’ is quantity of gas absorbed by m unit mass of solid

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4
Q

What is the formulaic representation of Freundlich Adsorption Theorem?

A

Freundlich Adsorption Theorem is given by:

log x/m = log k + 1/n log P

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5
Q

Why is adsoption always exothermic?

A

Adsorption is always exothermic because in Adsoption there is development of inter particle attractions between adsorbate and adsorbent

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6
Q

Out of NH3 and CO2, which gas will get absorbed more easily on the surface of activated charcoal and why?

A

NH3 will be absorbed more easily on the surface of charcoal because it has higher critical temperature due to Van Der Waal force of attraction

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7
Q

Distinguish between Freundlich Adsorption Theorem and Langmuir Adsoption Theorem

A

Freundlich Adsorption Theorem fails at high pressure of gas whereas Langmuir adsorption isotherm does not as its based on kinetic theory of gas and involves two processes ie adsoption and desorption

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8
Q

Say something about Zeolites

A

Zeolites are the shape selective catalysts having honey comb structure. Zeolite Catalyst ZSM-5 is used in petroleum industry to convert alcohols into gasoline by dehydration

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9
Q

What does Sucrose give in presence of Invertase?

A

Sucrose→→Invertase→→ Glucose + Fructose(Inversion of Cane Sugar)

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10
Q

What does Maltose give in presence of Maltase?

A

Maltose→→Maltase→→ Glucose + Glucose( Yeah its correct )

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11
Q

What does Lactose give in presence of Lactase?

A

Lactose→→Lactase→→Glucose + Galactose

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12
Q

What does Glucose give in presence of Zymase?

A

Glucose→→Zymase→→Ethyl Alcohol + CO2

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13
Q

What does Protein give in presence of Pepsin?

A

Protein→→Pepsin→→Peptides

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14
Q

What does Milk give in presence of lactobacilli enzyme?

A

Milk→→Lactobacilli Enzyme→→Curd

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15
Q

What are emulsions ?

A

Emulsions are liquid-liquid colloidal systems. Eg- Milk, Cream

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16
Q

What are sols?

A

Sols are Solid( Dispersed Phase ) and Liquid ( Dispersion Medium ) solution
Eg of sol is Gum

17
Q

What are Gels?

A

Gels are liquid-solid solution

Ex of gels are Jellies and cheese

18
Q

Give two examples of Lyophillic sol and Lyophobic sols

A

Lyophillic sols : Metal Sol, Metal Sulphides/Hydroxides

Lyophobic sols: Gum/Gelatin/Starch/Rubber

19
Q

Say something about Hardy Schulze rule?

A

Greater is the valency of the oppositely charged ion of the electrolyte being added, the faster is the coagulation