Substances From The Earth Part3 Flashcards

1
Q

What happens in terms of oxygen in an oxidation and reduction reaction?

A

Oxidation: The gain of oxygen by a substance.
Reduction: The loss of oxygen by a substance.

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2
Q

Describe the reaction of magnesium with oxygen.

A

• 2Mg(s) + 02(g) → 2MgO(s)
• Magnesium gains oxygen (oxidised), and oxygen loses oxygen (reduced).
• Magnesium is the reducing agent, and oxygen is the oxidising agent.

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3
Q

Describe the reaction of lead (Il) oxide with carbon.

A

• 2PbO(s) + C(s) → 2Pb(s) + CO2(g)
• Lead (II) oxide loses oxygen (reduced), and carbon gains oxygen (oxidised).
• Carbon is the reducing agent, and lead (Il) oxide is the oxidising agent.

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4
Q

How do you identify oxidising and reducing agents in a redox reaction?

A

• Oxidising agent: The substance that gains oxygen (gets reduced).
• Reducing agent: The substance that loses oxygen (gets oxidised).

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5
Q

Describe the reaction where hydrogen is added to ethene.

A

• C2Ha(g) + H2(g) → C2H6(g)
• Ethene (C2H4) gains hydrogen to form ethane (CHs), so it is reduced.
• Ethene is the oxidising agent, and hydrogen is the reducing agent.

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6
Q

Describe the reaction where hydrogen is removed from hydrogen sulfide.

A

•H2S(g) + Cl(g) → S(s) + 2HCl(g)
• Hydrogen sulfide (HS) loses hydrogen and is oxidised to sulfur (S).
• Hydrogen sulfide is the reducing agent, and chlorine is the oxidisin agent as it gains hydrogen.

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7
Q

How do you identify the oxidising and reducing agents when hydrogen is involved?

A

• Oxidising agent: The substance that gains hydrogen and is reduced.
• Reducing agent: The substance that loses hydrogen and is oxidised.

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8
Q

What happens in the reaction C2H4(g) +
H2(g) → C2Hь(g)?
.

A

• Ethene (CHa) gains hydrogen and becomes ethane (CHo), so it is reduced.
• Ethene is the oxidising agent, and hydrogen is the reducing agent.

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9
Q

What happens in the reaction HeS(g) +
C|(g) → S(s) + 2HC|(g)?

A

• Hydrogen sulfide (HS) loses hydrogen and is oxidised to sulfur (S).
• Hydrogen sulfide is the reducing agent, and chlorine is the oxidising agent as it gains hydrogen.

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10
Q

How can redox reactions be interpreted in terms of electron transfer?

A

• Oxidation: The process of losing electrons.
• Reduction: The process of gaining electrons.
• Oxidising agent: The electron acceptor.
• Reducing agent: The electron donor.

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11
Q

What happens in the reaction 2Mg(s) +
02(g) → 2MgO(s)?

A

• Magnesium (Mg): Loses electrons to form
Mg? ions, so it is oxidised.
• 2Mg → 2Mg2++ 4e
• Oxygen (02): Gains electrons to form O- ions, so it is reduced.
• 02+4e → 202-
• Magnesium is the reducing agent because it donates electrons.
• Oxygen is the oxidising agent because it accepts electrons.

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12
Q

What happens in the reaction 2Na(s) +
C|(g) → 2NaCl(s)?

A

• Sodium (Na): Loses electrons to form Na* ions, so it is oxidised.
• 2Na → 2Nat + 2e-
• Chlorine (Clz): Gains electrons to form Clions, so it is reduced.
• Cla + 2e* → 2Cl
Sodium is the reducing agent because it
donates electrons.
Chlorine is the oxidising agent because it
accepts electrons.

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13
Q

What is the oxidation number of elements in their free state?

A

• All elements in the free state (uncombined with any other elements) have an oxidation number of zero.
• Examples: Fe(s), Na(s), S(s), C(s), C/(g).

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14
Q

What is the oxidation number of simple ions?

A

• The oxidation number of a simple ion is the same as the charge on the ion.
• Examples: Na* (oxidation number +1), CI-(oxidation number -1).
Flashcard 45: Oxidation

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15
Q

What is the oxidation number of simple ions?

A

• The oxidation number of a simple ion is the same as the charge on the ion.
• Examples: Na* (oxidation number +1), CI-(oxidation number -1).
Flashcard 45: Oxidation

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16
Q

What are the oxidation numbers of Group 1, 2, and 3 metal ions?

A

• Group 1: +1 (e.g., Na, K).
• Group 2: +2 (e.g., Ca?, Mgz).
• Group 3: +3 (e.g., Als+).

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17
Q

What is the oxidation number of Group 7 non-metal ions?

A

• Group 7: -1 (e.g., Cl, Br).

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18
Q

What is the oxidation number of hydrogen in different compounds?

A

• +1 when combined with non-metals (e.g., hydrogen chloride, HCI).
• -1 when combined with metals (e.g., sodium hydride, NaH).

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19
Q

What is the oxidation number of the oxide ion (O2-)?

A

• The oxidation number of the oxide ion is always -2.

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20
Q

How is the oxidation number of a polyatomic ion determined?

A

• The oxidation number of a polyatomic ion is the same size and sign of the charge of the polyatomic ion.
• Example: The sulfate ion (SO,?*) has an oxidation number of -2.

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21
Q

How do oxidation and reduction occur in the reaction 2Na(s) + C|(g) → 2NaCl(s)?

A

• Electron transfer:
• Sodium loses electrons to form Nations:
2Na → 2Na* + 2e (oxidation).
• Chlorine gains electrons to form Clions: Cla
+ 2e → 2Cl (reduction).
• Oxidation numbers:
• Sodium changes from O to +1 (oxidation).
• Chlorine changes from O to -1 (reduction).

22
Q

What happens when coke burns with oxygen in the blast furnace?

A

• The coke (carbon) reacts with oxygen to produce carbon dioxide:
• C(s) + 02(g) → COz(g).
• In this reaction, carbon is oxidised (it gains oxygen).

23
Q

How do oxidation numbers change in the reaction between iron ore and carbon monoxide in the blast furnace?

A

• In Fe203 + 3CO → 2Fe + 3C02:
• Iron: The oxidation number decreases from +3 (in FezO3) to 0 (in Fe), so iron is reduced.
• Carbon: The oxidation number increases from +2 (in CO) to +4 (in COz), so carbon is oxidised.

24
Q

What is a net ionic equation?

A

A net ionic equation represents the actual chemical reaction that occurs in a solution, showing only the ions and compounds that are involved in the reaction. Spectator ions, which do not take part in the reaction, are not included in the net ionic equation.

25
What are spectator ions in a net ionic equation?
Spectator ions are ions that remain unchanged during the reaction. They are present in the solution but do not participate in the chemical change, so they are not included in the net ionic equation.
26
What happens when NaCl dissolves in
• NaCl dissociates in water into Na* and Cl- ions. • lonic Equation: NaCl (s) → Na†(ag) + Cl (aq)
27
What are some uses of carbon nanotubes?
• Reinforcing materials (e.g., in sports equipment and aerospace materials). • Electronics (e.g., in flexible displays and nano-circuits). • Nanotechnology (e.g., targeted drug delivery, sensors).
28
What are the key properties of carbon nanotubes?
• High tensile strength (resistant to stretching and breaking). • Conduct electricity (delocalized electrons). • Lightweight and strong. • Large surface area (useful for adsorption and catalysts).
29
What are fullerenes?
Fullerenes are carbon allotropes that form hollow tubes or spheres, such as carbon nanotubes and buckyballs (Coo).
30
What are carbon nanotubes?
Carbon nanotubes are cylindrical fullerenes made by rolling up graphene into a hollow tube.
31
What are allotropes?
Allotropes are different forms of the same element in the same state of matter.
32
What are the main allotropes of carbon?
Diamond, graphite, graphene, and carbon nanotubes.
33
What type of bonding is found in diamond, graphite, and graphene?
Giant covalent bonding, where many carbon atoms are joined by strong covalent bonds.
34
How are carbon atoms arranged in graphite?
• Each carbon atom is bonded to three other carbon atoms in a hexagonal layered structure. • Layers are held together by weak forces and can slide over each other.
35
What are the half-equations for the reaction between iron and copper(Il) sulfate?
• Oxidation (Iron loses electrons): Fe(s) → Fe?+(aq) + 2è • Reduction (Copper ions gain electrons): Cu?+(ag) + 2è → Cu(s)
36
In the reaction between iron and copper (Il) sulfate, what are the oxidizing and reducing agents?
• Oxidizing agent: Copper(Il) ions (Cu?*) because they gain electrons. • Reducing agent: Iron (Fe) because it donates electrons.
37
Why can graphite conduct electricity?
• Each carbon atom has one delocalized electron that is free to move. • These electrons allow graphite to conduct electricity.
38
What are the key properties of graphite?
• Conducts electricity (due to delocalized electrons). • Slippery (layers slide over each other). • High melting point (strong covalent bonds in layers).
39
What are some uses of graphite?
• Electrodes (batteries, electrolysis). • Lubricant (reduces friction in electric motor brushes).
40
Why is diamond so hard?
• Each carbon forms four strong covalent bonds, creating a rigid network. • This makes diamond extremely hard and resistant to scratches.
41
Can diamond conduct electricity? Why or why not?
• No, because all electrons are bonded, so there are no free-moving electrons.
42
How does the reactivity of halogens change down the group?
The reactivity of halogens decreases down the group. Order of reactivity: Chlorine > Bromine > lodine.
43
What happens in a displacement reaction between bromine and iodide ions?
Bromine is more reactive than iodine and displaces iodide ions from solution. Bromine solution (orange) reacts with sodium iodide to form a brown solution (iodine).
44
What happens to iodide ions in the displacement reaction with sodium iodide?
lodide ions lose electrons (are oxidized) and become iodine (lz).
45
What is the OIL RIG mnemonic for redox reactions?
OIL RIG: • Oxidation Is Loss of electrons. • Reduction Is Gain of electrons.
46
What happens in the displacement reaction between iron and copper(Il) sulfate?
Iron displaces copper from copper(Il) sulfate solution because iron is more reactive than copper. • The blue solution turns green (iron (I1) sulfate forms). • Red-brown copper is deposited on the iron nail.
47
What are some uses of diamond?
• Cutting tools (diamond-tipped glass cutters, oil rig drills). • Jewelry (due to hardness and brilliance).
48
What are the key properties of diamond?
• Very hard (strong covalent bonds). • High melting point (strong covalent bonds). • Does not conduct electricity (no free electrons).
49
How does electrical conductivity differ between diamond and graphite?
• Diamond: Does not conduct electricity (no free electrons). • Graphite: Good conductor (delocalized electrons).
50
What is graphene?
Graphene is a single-atom-thick layer of graphite, where carbon atoms form a hexagonal structure with strong covalent bonds.