Structure of Atoms, Periodic Table & Chemical Bonding Flashcards

1
Q

Describe the composition of an atomic nucleus.

A

An atomic nucleus is composed of protons, which have a positive charge (+1), and neutrons, which have no charge (0).

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2
Q

Define isotopes and their significance.

A

Isotopes are atoms of the same element that have different numbers of neutrons, resulting in different mass numbers. They are significant in various applications, including radiometric dating and medical diagnostics.

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3
Q

How do radioactive isotopes decay?

A

Radioactive isotopes undergo spontaneous decay of the atomic nucleus, losing energy and particles. For example, one neutron can decay into a proton, transforming carbon-14 into nitrogen-14.

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4
Q

Explain the concept of half-life in radioactive isotopes.

A

Half-life is the time it takes for 50% of a parent isotope to decay. This rate is fixed for each isotope and is used in various scientific applications.

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5
Q

What are the applications of radioactive isotopes in medicine?

A

Radioactive isotopes are used as diagnostic tools in medicine, such as in Positron Emission Tomography (PET) radiotracers, which help visualize metabolic activity in tissues.

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6
Q

Describe the structure of atoms in terms of electrons.

A

Atoms have electrons, which are negatively charged (-1), surrounding the nucleus. The number of electrons typically equals the number of protons in a neutral atom.

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7
Q

How are elements distinguished from one another?

A

Elements are distinguished by the number of protons in their atomic nuclei, which is known as the atomic number.

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8
Q

What is the significance of the periodic table in chemistry?

A

The periodic table organizes elements based on their atomic number and properties, providing a framework for understanding chemical behavior and relationships.

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9
Q

Explain the difference between intramolecular and intermolecular bonding.

A

Intramolecular bonding refers to the forces that hold atoms together within a molecule (e.g., ionic, covalent, metallic bonds), while intermolecular interactions are forces between molecules (e.g., van der Waals forces, hydrogen bonds).

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10
Q

What role do van der Waals forces play in molecular interactions?

A

Van der Waals forces are weak intermolecular interactions that occur between molecules, influencing properties such as boiling and melting points.

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11
Q

Describe the significance of hydrogen bonds in biological systems.

A

Hydrogen bonds are crucial in biological systems as they help stabilize the structures of proteins and nucleic acids, such as DNA.

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12
Q

How does the atomic mass relate to the mass number of an element?

A

The atomic mass of an element is approximately equal to its mass number, which is the sum of protons and neutrons in the nucleus.

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13
Q

What is the atomic mass of sodium (Na)?

A

The standard atomic mass of sodium (Na) is approximately 22.990.

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14
Q

Define the term ‘element’ in chemistry.

A

An element is a pure substance that cannot be broken down into simpler substances by chemical reactions and is defined by its unique number of protons.

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15
Q

How do unstable isotopes differ from stable isotopes?

A

Unstable isotopes undergo radioactive decay, losing energy and particles over time, while stable isotopes do not change and remain constant.

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16
Q

What is the role of carbon-14 in scientific studies?

A

Carbon-14 is used in radiometric dating to determine the age of fossils and archaeological artifacts due to its radioactive properties.

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17
Q

Describe the relationship between atomic number and element identity.

A

The atomic number, which is the number of protons in an atom’s nucleus, uniquely identifies an element and determines its position in the periodic table.

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18
Q

Describe the arrangement of electrons in an atom.

A

Electrons localize around the atomic nucleus in different electron shells, also known as energy levels.

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19
Q

Define the term ‘subshell’ in the context of electron configuration.

A

Subshells are divisions of energy levels that contain orbitals, which can be s, p, d, or f.

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20
Q

How many electrons can a single orbital contain?

A

Each orbital can contain up to 2 electrons, which spin in opposite directions to minimize repulsion.

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21
Q

What shapes are associated with the different types of orbitals?

A

s orbitals are spherical, p orbitals are dumbbell-shaped, d orbitals resemble a four-leaf clover, and f orbitals have a tetrahedral shape.

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22
Q

Explain the concept of electron configuration using Sodium as an example.

A

Sodium (11 electrons) has the electron configuration 1s2, 2s2, 2p6, 3s1.

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23
Q

What is the electron configuration for Copper?

A

Copper (29 electrons) has the electron configuration 1s2, 2s2, 2p6, 3s2, 3p6, 3d10, 4s1.

24
Q

Differentiate between cations and anions.

A

Cations are positive ions formed when metal atoms lose electrons, while anions are negative ions formed when non-metal atoms gain electrons.

25
Q

How are elements organized in the periodic table?

A

Elements are arranged in order of increasing atomic number, organized into groups (columns) and periods (rows).

26
Q

What is electronegativity and how does it vary in the periodic table?

A

Electronegativity is the power of an atom to attract a pair of electrons in a chemical bond; it increases across a period and decreases down a group.

27
Q

Describe the characteristics of transition metals.

A

Transition metals are elements in the d block of the periodic table, known for their ability to form colored compounds and having unique properties.

28
Q

What is the significance of the principal quantum number in electron configuration?

A

The principal quantum number indicates the energy level of an electron in an atom, determining its distance from the nucleus.

29
Q

How do the number of electrons relate to the number of shells in an atom?

A

The number of electrons determines how many shells are filled; each shell can hold a specific maximum number of electrons.

30
Q

What is the role of ATP in relation to ions in cells?

A

ATP helps balance the positive charge of ions like Na+ and Ca2+ in cells.

31
Q

Explain the concept of orbitals in three-dimensional space.

A

Orbitals are three-dimensional spaces around the nucleus where electrons are likely to be found.

32
Q

How does the arrangement of elements in the periodic table reflect their chemical properties?

A

Elements with similar chemical properties are grouped together in columns, while rows indicate the filling of energy levels.

33
Q

Describe ionic bonds.

A

Ionic bonds are formed through the electrostatic attraction between two oppositely charged ions, typically involving the transfer of electrons from metal atoms (which lose electrons) to non-metal atoms (which gain electrons).

34
Q

Define covalent bonds.

A

Covalent bonds are formed when one or more pairs of valence electrons are shared between atoms, commonly occurring between non-metal elements.

35
Q

How do ionic compounds form?

A

Ionic compounds form when metal atoms lose electrons to become positively charged ions, while non-metal atoms gain those electrons to become negatively charged ions, resulting in the formation of salts.

36
Q

What are the characteristics of metallic bonds?

A

Metallic bonds are characterized by the electrostatic attraction between delocalised electrons and metal ions, allowing metals to conduct electricity and heat due to the mobility of these electrons.

37
Q

Explain the structure of salts.

A

Salts are organized in three-dimensional structures known as ionic lattices or crystals, which exhibit a cubic arrangement.

38
Q

How do covalent bonds differ in polarity?

A

Covalent bonds can be non-polar, where atoms have equal electronegativity, or polar, where atoms have different electronegativities, resulting in a partial charge.

39
Q

What is the significance of valence electrons in chemical bonding?

A

Valence electrons are crucial in determining the chemical behavior and reactivity of atoms, as they are involved in the formation of chemical bonds.

40
Q

Describe the formation of a water molecule.

A

A water molecule (H2O) is formed when two hydrogen atoms each share one pair of electrons with an oxygen atom, resulting in two single covalent bonds.

41
Q

How do metallic bonds contribute to the properties of metals?

A

Metallic bonds allow for the presence of delocalised electrons, which can move freely through the metal, enabling metals to conduct electricity and heat effectively.

42
Q

What is a non-polar covalent bond?

A

A non-polar covalent bond occurs between atoms with equal electronegativity, resulting in an equal sharing of electrons.

43
Q

What is a polar covalent bond?

A

A polar covalent bond occurs between atoms with different electronegativities, leading to an unequal sharing of electrons and the creation of a partial charge.

44
Q

How do covalent bonds relate to molecules?

A

Atoms linked by covalent bonds are referred to as molecules, which can consist of two or more atoms sharing electrons.

45
Q

Explain the concept of delocalised electrons in metallic bonds.

A

Delocalised electrons in metallic bonds are valence electrons that are not bound to any specific atom and can move freely throughout the metal structure, contributing to conductivity.

46
Q

What happens to noble gases in terms of bonding?

A

Noble gases have full outer electron shells, which means they do not form bonds and are generally unreactive.

47
Q

Describe the electron configuration of a sodium atom.

A

The electron configuration of a sodium atom is 1s2, 2s2, 2p6, 3s1, indicating it has one valence electron in its outermost shell.

48
Q

How many covalent bonds does an oxygen molecule (O2) have?

A

An oxygen molecule (O2) has a double bond, formed by two pairs of shared electrons between the two oxygen atoms.

49
Q

What is the role of electronegativity in polar covalent bonds?

A

Electronegativity determines the strength of an atom’s attraction for shared electrons; in polar covalent bonds, the atom with higher electronegativity attracts the shared electrons more strongly.

50
Q

Describe London dispersion forces.

A

London dispersion forces are the weakest intermolecular forces, also known as temporary dipole-induced dipole forces, that form between non-polar molecules due to transitory uneven electron distribution.

51
Q

Explain dipole-dipole forces.

A

Dipole-dipole forces are permanent intermolecular forces that occur between polar molecules, where opposite charged poles attract each other, and they are stronger than London dispersion forces but only about 1% of a covalent bond’s strength.

52
Q

How do gecko lizards utilize van der Waals forces?

A

Gecko lizards can adhere to walls thanks to van der Waals forces that form between tiny hairy structures on their feet and the surface, involving hundreds of thousands of these forces.

53
Q

Define hydrogen bonds and their significance.

A

Hydrogen bonds are the strongest form of intermolecular force, involving hydrogen bound to oxygen, nitrogen, or fluorine, resulting in highly polar molecules with permanent dipoles.

54
Q

What role do weak interactions play in macromolecules?

A

Weak interactions such as van der Waals forces, hydrogen bonds, and ionic bonds are fundamental in forming the 3D structure of macromolecules like proteins and nucleic acids.

55
Q

What is the significance of electronegativity in hydrogen bonds?

A

Electronegativity creates a large difference between atoms in hydrogen bonds, leading to highly polar molecules and strong attractions between hydrogen and electron pairs of other molecules.

56
Q

How do weak interactions contribute to biological processes?

A

Weak interactions are crucial for the stability and functionality of biological macromolecules, influencing their 3D structures and interactions.

57
Q

Define molarity in the context of chemistry.

A

Molarity is a measure of the concentration of a solute in a solution, expressed as the number of moles of solute per liter of solution.