Acids And Bases Flashcards

1
Q

Define a Brønsted-Lowry acid.

A

A Brønsted-Lowry acid is a proton donor.

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2
Q

Give an example of a Brønsted-Lowry acid.

A

Ammonium ions (NH4+).

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3
Q

Define a Brønsted-Lowry base.

A

A Brønsted-Lowry base is a proton acceptor.

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4
Q

Give an example of a Brønsted-Lowry base.

A

Hydroxide ions (OH-).

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5
Q

Describe the relationship between acid strength and dissociation.

A

A strong acid completely dissociates to ions in solution, while a weak acid only slightly dissociates.

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6
Q

What pH range is associated with strong acids?

A

Strong acids have a pH range of 0-1.

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7
Q

What pH range is associated with weak acids?

A

Weak acids have a pH range of 3-5.

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8
Q

Explain the pH range for strong bases.

A

Strong bases have a pH range of 12-14.

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9
Q

Explain the pH range for weak bases.

A

Weak bases have a pH range of 9-11.

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10
Q

How can substances be classified as acids or bases?

A

Substances can be classified as acids or bases based on their interaction with protons.

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11
Q

What does acid strength not refer to?

A

Acid strength does not refer to the concentration of a solution.

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12
Q

Define pH.

A

pH is a measure of acidity and alkalinity, represented on a logarithmic scale from 0 to 14, indicating the concentration of H+ ions in a solution.

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13
Q

Describe the significance of a pH of 0.

A

A pH of 0 indicates an acidic solution with a high concentration of H+ ions.

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14
Q

Describe the significance of a pH of 14.

A

A pH of 14 indicates a basic solution with a low concentration of H+ ions.

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15
Q

How can the concentration of H+ ions be determined?

A

The concentration of H+ ions can be determined if the pH of the solution is known.

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16
Q

Explain the relationship between strong acids and H+ ion concentration.

A

The concentration of H+ ions in a solution is equivalent to the concentration of a strong acid, as strong acids completely dissociate into ions.

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17
Q

What is the ionic product of water (Kw) at 25°C?

A

At 25°C, the ionic product of water (Kw) has a constant value of 1 x 10^-14.

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18
Q

How does temperature affect the ionic product of water?

A

As temperature changes, the value of the ionic product of water (Kw) also changes.

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19
Q

Describe the nature of the forward reaction in the equilibrium of water.

A

The forward reaction in the equilibrium of water is endothermic and is favored when the temperature of the water is increased.

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20
Q

What happens to H+ ion production as the temperature of water increases?

A

As the temperature of water increases, more H+ ions are produced, making the water more acidic.

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21
Q

Describe the dissociation of weak acids and bases in solution.

A

Weak acids and bases only slightly dissociate in solution, forming an equilibrium mixture.

22
Q

Define the equilibrium dissociation constant for weak acids.

A

The equilibrium dissociation constant for weak acids is denoted as Ka.

23
Q

How can pKa be used in relation to weak acids and bases?

A

pKa can be used to find the concentration of hydrogen ions

24
Q

Explain the method to find pH when HA is in excess.

A

When HA is in excess, use the concentrations of [HA] and [A - ] along with Ka to find [H + ], then calculate pH.

25
Q

What is the approach when A - is in excess?

A

When A - is in excess, use the ion product of water, Kw, to find [H + ], then calculate pH.

26
Q

How is pKa related to pH when HA equals A - ?

A

When HA equals A - , pKa is equal to pH, so you can find pKa directly.

27
Q

Describe a pH titration curve.

A

A pH titration curve shows how the pH of a solution changes during an acid-base reaction.

28
Q

What is the significance of the neutralisation point in a titration curve?

A

The neutralisation point is identified as a large vertical section in the titration curve, indicating the equivalence point of the acid-base reaction.

29
Q

Describe the process of investigating the pH of an acid-base reaction.

A

Alkali is slowly added to an acid while measuring the pH with a pH probe, or vice versa. Smaller added volumes yield a more accurate pH curve.

30
Q

Define the neutralization point for a strong acid and strong base reaction.

A

The neutralization point for a strong acid and strong base reaction occurs around pH 7.

31
Q

How does the neutralization point differ between strong acids and weak bases?

A

For a strong acid and weak base reaction, the neutralization point is less than pH 7, indicating a more acidic solution.

32
Q

What is the expected pH when a weak acid reacts with a strong base?

A

The expected pH when a weak acid reacts with a strong base is greater than pH 7, indicating a more basic solution.

33
Q

Explain the neutralization point for weak acid and weak base combinations.

A

The neutralization point for weak acid and weak base combinations is normally around pH 7, but it can be hard to determine accurately.

34
Q

How does the volume of alkali added affect the accuracy of the pH curve?

A

The smaller the added volumes of alkali, the more accurate the pH curve produced during the investigation.

35
Q

Describe the role of specific indicators in chemical reactions.

A

Specific indicators are used for specific reactions as they indicate a pH change within a certain range.

36
Q

Define methyl orange and its use in titrations.

A

Methyl orange is an indicator used for reactions with a more acidic neutralisation point, appearing orange in acids and turning yellow at the neutralisation point.

37
Q

Explain the color change of phenolphthalein in different pH environments.

A

Phenolphthalein is pink in alkalis and turns colourless at the neutralisation point, making it suitable for reactions with a more basic neutralisation point.

38
Q

How does the choice of indicator affect titration results?

A

The correct indicator must be selected based on the chemicals used in a titration to accurately reflect the pH change.

39
Q

What components make up an acidic buffer solution?

A

An acidic buffer solution contains a weak acid and the salt of that weak acid.

40
Q

Identify the components of a basic buffer solution.

A

A basic buffer solution consists of a weak base and the salt of that weak base.

41
Q

Describe the function of a buffer solution when an acid is added.

A

When an acid is added to a buffer solution, it resists a change in pH by reacting with the buffer components, such as ethanoate ions, to form the weak acid.

42
Q

How does a buffer solution maintain pH stability?

A

A buffer solution maintains pH stability by neutralizing small amounts of added acid or base, preventing significant changes in pH.

43
Q

Define a buffer solution in terms of pH changes.

A

A buffer solution is defined as a solution that can resist changes in pH when small volumes of acid or base are added.

44
Q

Describe the process of calculating pH for an acid and base buffer system.

A

Find the number of moles of each species, calculate their concentration at equilibrium using the total volume, and use Ka to find [H+] and therefore pH.

45
Q

How does adding small volumes of acid affect the pH of a buffer solution?

A

Adding small amounts of acid (H+) increases the concentration of the acid in the buffer solution, making the overall solution slightly more acidic.

46
Q

What happens to the pH of a buffer solution when small amounts of base are added?

A

Adding small amounts of base (OH-) decreases the concentration of acid in the buffer solution, making the overall solution slightly more basic.

47
Q

Define the role of buffer solutions in biological systems.

A

Buffer solutions help maintain a specific pH, which is crucial for the proper functioning of enzymes and reactions in living organisms.

48
Q

Explain the significance of buffer solutions in nature.

A

Buffer solutions are important for regulating systems in nature, ensuring that biological processes can occur within the required pH range.

49
Q

How do you calculate pH for an acid and salt buffer system?

A

Find the moles of the salt and use Ka to determine the pH.

50
Q

What is the typical change in pH when small volumes of acid or base are added to a buffer solution?

A

The pH of a buffer solution typically changes by about 0.1 or 0.01 units when small volumes of acid or base are added.