Structure of Atom Flashcards

1
Q

What is radiation

A

A mode of transference of energy

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2
Q

What is wavenumber

A

It is the number of waves per metre. (1/wavelength )

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3
Q

What is the electromagnetic spectrum

A

The arrangement of different types of electromagnetic radiations in decreasing order of their wavelengths

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4
Q

State the order of the electromagnetic spectrum

A

radio>micro>infra>visible>UV>X>gamma>cosmic

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5
Q

Why couldnt E.W.T explain black body radiation

A

Because according to it, only one colour should have been emitted irrespective of temperature

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6
Q

What is photoelectric effect

A

The ejection of electrons when a radiation of threshold frequency falls on the surface on the metal

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7
Q

State the postulates of Plank’s Quantum theory

A
  1. Energy is absorbed or emitted discontinuously in small packets
  2. Each packet of energy is a quantum and the quantum of light is a photon
  3. Energy of photon = hv
  4. A body can absorb or emit only a whole number multiple of one photon
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8
Q

What is emission spectra

A

It is the spectrum obtained when radiations emitted by the excited substance are analyzed by a spectroscope. It has bright lines separated by dark spaces

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9
Q

What is absorption spectrum

A

The spectrum is obtained when white light is passed through a substance in a gaseous or solution state. It consists of a band of colours with dark lines

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10
Q

Name the scientists which study the different parts of the line spectrum

A

UV - Lyman - n1
Visible - Balmer - n2
Infrared - Paschen - n3
Infrared - Brackett - n4
Infrared - Pfund - n5

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11
Q

How to calculate the wavelength for hydrogen spectrum

A

(1/Wavelenght) = 109678(1/n1^2 - 1/n2^2) where n1 is the final shell

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12
Q

What is the energy of a shell

A

(-2 * π^2 * Z^2 * e^4 * m)/ (n^2 * h^2)

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13
Q

What is Bohr’s model of atom

A
  1. Electrons move in fixed non-radiating orbits called stationary states
  2. Each stationary state has a fixed energy so it is known as energy levels
  3. Only shells with angular momentum (mvr) which is a whole no. multiple oh h/2pi is permitted
  4. Energy is quantized
  5. electrons have a normal state with doesn’t lose energy
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14
Q

How to calulate number of lines in spectru

A

n(n-1)/2 where n is the outermost shell

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15
Q

What is Heisenberg theory

A

It is impossible to know the exact position and momentum of a subatomic particle at the same time

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16
Q

What does De Broglie state

A

That all materials posses in motion posses wave nature
wavelength = h / mv

17
Q

The mathematical statement of Heisenberg uncertainty principle

A

Δx . Δp =>= h/4π

18
Q

What are quantum numbers

A

They are the index numbers which are used to specify the position and energy of an electron in the atom

19
Q

What are the four quantum number

A

Principal (n) - energy level
Azimuthal (l) - subshell
Magnetic (m) - orientation of orbital
Spin (s) = +1/2, -1/2

20
Q

How to calculate the total number of electrons in a subshell

A

2(2l+1)

21
Q

What is the maximum number of orbitals in a shell

A

n^2

22
Q

What does Pauli’s exclusion principle state

A

No two electrons in an orbital of an atom can have the same 4 quantum numbers ( no two electrons with same spin can fill an orbital)

23
Q

How many nodes does s orbital have

A

(n-1) when n is the energy level

24
Q

How many nodes does p orbital have

A

(n-2)

25
Q

What are degenerate orbitals

A

Orbitals having the same energy