structure and bonding Flashcards
what is monatomic bonding
noble gases exist as single atoms - they are monatomic
what is metallic bonding
electrostatic force of attraction between positive metal centres and delocalised electrons
what is covalent molecular bonding
electrostatic force of attraction between 2 positive nuclei and a pair of electrons
what are odd examples of covalent molecular bonding
phosphorus (P4)
sulfur (S8)
buckminster fullerene (c60)
what is covalent network bonding
only boron, silicon and carbon can do this
what is ionic bonding
the electrostatic force of attraction between positive and negative ions
what is pure covalent
- sometimes called non polar covalent
- two nuclei are equally attracted to the same pair of shared electrons
- exists between atoms with the same/similar electronegativity eg diatomic molecules
what is polar covalent
- two nuclei are unequally attracted to the same pair of shared electrons
- an atom with higher electronegativity has a greater attraction to the bonding electrons
- bonding electrons are pulled closer to the atom causing a permanent dipole
what happens if there is a large difference in electronegativity
then one atom loses its electron to the other
usually between metal and non metal elements
can a molecule have polar bonds and be non polar
yes
do polar or non polar molecules have permanent dipoles
polar molecules
is mp and bp higher in polar or non polar molecules and why
polar because they have increased intermolecular forces
example of non polar solvent
hexane
example of polar solvent
water
explain like dissolves like
polar substances are soluble in polar solvents and non polar substances are soluble in non polar solvents