structure and bonding Flashcards

1
Q

what is monatomic bonding

A

noble gases exist as single atoms - they are monatomic

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2
Q

what is metallic bonding

A

electrostatic force of attraction between positive metal centres and delocalised electrons

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3
Q

what is covalent molecular bonding

A

electrostatic force of attraction between 2 positive nuclei and a pair of electrons

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4
Q

what are odd examples of covalent molecular bonding

A

phosphorus (P4)
sulfur (S8)
buckminster fullerene (c60)

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5
Q

what is covalent network bonding

A

only boron, silicon and carbon can do this

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6
Q

what is ionic bonding

A

the electrostatic force of attraction between positive and negative ions

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7
Q

what is pure covalent

A
  • sometimes called non polar covalent
  • two nuclei are equally attracted to the same pair of shared electrons
  • exists between atoms with the same/similar electronegativity eg diatomic molecules
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8
Q

what is polar covalent

A
  • two nuclei are unequally attracted to the same pair of shared electrons
  • an atom with higher electronegativity has a greater attraction to the bonding electrons
  • bonding electrons are pulled closer to the atom causing a permanent dipole
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9
Q

what happens if there is a large difference in electronegativity

A

then one atom loses its electron to the other
usually between metal and non metal elements

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10
Q

can a molecule have polar bonds and be non polar

A

yes

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11
Q

do polar or non polar molecules have permanent dipoles

A

polar molecules

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12
Q

is mp and bp higher in polar or non polar molecules and why

A

polar because they have increased intermolecular forces

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13
Q

example of non polar solvent

A

hexane

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14
Q

example of polar solvent

A

water

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15
Q

explain like dissolves like

A

polar substances are soluble in polar solvents and non polar substances are soluble in non polar solvents

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16
Q

what are the 3 van der waals forces in order of strength

A

ldfs, permanent dipole, hydrogen bonding

17
Q

explain ldfs

A

electrons are constantly moving, can lead to uneven electron distribution at times which creates a temp dipole which induces another temp dipole in another atom

creates weak electrostatic force of attraction between the atoms

18
Q

what elements does ldfs occur

A

all

19
Q

which molecules will have a permanent dipole

A

polar molecules

20
Q

what is hydrogen bonding

A

a type of permanent dipole force that occurs between hydrogen and NOF

21
Q

how does ice melt

A

stable hydrogen bonds break and reform

22
Q

melting point of ionic compounds

A

high

23
Q

melting points of covalent networks

A

high

24
Q

are ionic compounds solid at room temp

A

yes

25
Q

are covalent networks solid at room temp

A

yes

26
Q

what structure and bonding do all gasses and liquids

A

covalent molecular

27
Q

what type of bonding had conduction as a solid

A

metallic

28
Q

what kind of bonding has conduction as a liquid

A

metallic and ionic

29
Q

what kind of bonding has conduction as solutions

A

ionic