structure and bonding Flashcards

1
Q

what is monatomic bonding

A

noble gases exist as single atoms - they are monatomic

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2
Q

what is metallic bonding

A

electrostatic force of attraction between positive metal centres and delocalised electrons

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3
Q

what is covalent molecular bonding

A

electrostatic force of attraction between 2 positive nuclei and a pair of electrons

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4
Q

what are odd examples of covalent molecular bonding

A

phosphorus (P4)
sulfur (S8)
buckminster fullerene (c60)

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5
Q

what is covalent network bonding

A

only boron, silicon and carbon can do this

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6
Q

what is ionic bonding

A

the electrostatic force of attraction between positive and negative ions

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7
Q

what is pure covalent

A
  • sometimes called non polar covalent
  • two nuclei are equally attracted to the same pair of shared electrons
  • exists between atoms with the same/similar electronegativity eg diatomic molecules
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8
Q

what is polar covalent

A
  • two nuclei are unequally attracted to the same pair of shared electrons
  • an atom with higher electronegativity has a greater attraction to the bonding electrons
  • bonding electrons are pulled closer to the atom causing a permanent dipole
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9
Q

what happens if there is a large difference in electronegativity

A

then one atom loses its electron to the other
usually between metal and non metal elements

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10
Q

can a molecule have polar bonds and be non polar

A

yes

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11
Q

do polar or non polar molecules have permanent dipoles

A

polar molecules

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12
Q

is mp and bp higher in polar or non polar molecules and why

A

polar because they have increased intermolecular forces

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13
Q

example of non polar solvent

A

hexane

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14
Q

example of polar solvent

A

water

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15
Q

explain like dissolves like

A

polar substances are soluble in polar solvents and non polar substances are soluble in non polar solvents

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16
Q

what are the 3 van der waals forces in order of strength

A

ldfs, permanent dipole, hydrogen bonding

17
Q

explain ldfs

A

electrons are constantly moving, can lead to uneven electron distribution at times which creates a temp dipole which induces another temp dipole in another atom

creates weak electrostatic force of attraction between the atoms

18
Q

what elements does ldfs occur

19
Q

which molecules will have a permanent dipole

A

polar molecules

20
Q

what is hydrogen bonding

A

a type of permanent dipole force that occurs between hydrogen and NOF

21
Q

how does ice melt

A

stable hydrogen bonds break and reform

22
Q

melting point of ionic compounds

23
Q

melting points of covalent networks

24
Q

are ionic compounds solid at room temp

25
are covalent networks solid at room temp
yes
26
what structure and bonding do all gasses and liquids
covalent molecular
27
what type of bonding had conduction as a solid
metallic
28
what kind of bonding has conduction as a liquid
metallic and ionic
29
what kind of bonding has conduction as solutions
ionic