States of Matter Flashcards

1
Q

Describe the arrangement and properties of gases?

A

Gases have no fixed shape or volume.
They are far apart so can be compressed
Are randomly arranged
Can move freely from place to place in all directions.

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2
Q

Describe the arrangement and properties of liquids.

A

Liquids have no fixed shape but fixed volume.
Are close together, so liquids have a fixed volume and can only be compressed slightly.
Are randomly arranged
Have limited movement from place to place in all directions.

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3
Q

Describe the arrangement and properties of solids.

A

Solids have a fixed volume and shape.
They are usually in a regular arrangement.
Are touching each other so cannot be compressed.
Cannot change positions with each other, they can only vibrate.

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4
Q

What does the state of a substance at room temperature depend upon?

A

The state of a substance at room temperature depends upon its structure and bonding.

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5
Q

What are the four types of structures and bonding found in elements or compounds?

A

Simple molecular or simple atomic for e.g. CO2, Argon and noble gases.
Giant Ionic e.g. Sodium Chloride and Magnesium chloride.
Giant metallic e.g. Iron and Copper.
Giant molecular e.g Silicon (IV) Dioxide.

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6
Q

Define an ideal gas:

A

Ideal gas is a gas whose volume varies in proportion to the temperature and in inverse proportion to the pressure. Ideal gases have no intermolecular forces of attraction and zero particle volume. Noble gases approach ideal behaviour because of their low intermolecular forces.

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7
Q

Define a real gas.

A

A gas that does not obey the ideal gas law especially at low temperatures and high pressures.

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8
Q

What is the pressure of a gas due to?

A

The pressure of a gas is due to the collisions between the gas molecules and the wall of the container.

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9
Q

Explain the relationship between pressure and volume of a gas.

A

If we decrease the volume of a gas (at constant temperature) the molecules come close together and hit the walls of the container more often, so the pressure of the gas increases. THEREFORE the pressure and volume of a gas are inversely proportional to each other as long as the temperature and the quantity of the gas are kept constant.

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10
Q

How can the relationship between pressure and volume be represented mathematically?

A

The relationship between pressure and volume (at constant mass and temperature) can be represented mathematically as:

V ∝ 1/P

v=k/p where k is a constant

PV=K

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11
Q

Under what conditions will a molecule most likely behave as an ideal gas?

A

High Temperature because energetic particles can easily break intermolecular forces/easier to behave as a gas.
Low pressure as the particle are far apart and there would be a large gap between the molecules so volume would be negligible as compared to volume of container.

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12
Q

How can you change celsius into kelvin?

A

To change Celsius to Kelvin, add 273 to the celsius temperature.

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13
Q

What is the pressure of 101 325 Pascals in atmospheric pressure?

A

101 325 Pa=1.0 atmospheric pressure.

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14
Q

Explain the relationship between temperature and volume at a constant pressure.

A

When a gas is heated at constant pressure its volume increases. This is because the particles move faster and hit the walls of the container with greater force. For the pressure to be constant, the molecules must be further apart. For this volume increases.

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15
Q

How can the relationship between volume and temperature be expressed mathematically?

A

For an ideal gas:
V∝T (at constant pressure)

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16
Q

What is the ideal gas equation?

A

PV=nRT
where
P=pressure in Pa
v=volume in m3
n=number of moles (also known as Avogadro’s constant)
R=Molar gas constant
T=temperature in kelvin

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17
Q

What is the value of molar gas constant?

A

R=8.314 J K-1 Mol-1

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18
Q

How can volume be converted into its si base units from cm3 and dm3?

A

Volumes si base unit is m3.
1000cm3=1dm3
1000dm3=1m3
1cm3=10^-6m3
150dm3=150 x 10^-3m3

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19
Q

How can pressure be converted from its si base units from Kpa?

A

Pressure’s si base unit is Pa.
1kPa=1000Pa
1Kpa=10^3Pa

20
Q

At which conditions will a real gas most likely deviate from ideal gas behaviour?

A

At high pressure and low temperature.
This is because the molecules are close together, there are instantaneous dipole-induced dipole forces or permanent dipole dipole forces of attraction between the molecules. Attractive forces pull the molecules close towards each other and away from the walls of the container. The volume of the molecules is not negligible compared with the volume of the container.

21
Q

How can we calculate the molecular/molar /Mr mass using the equation pv=nRT

A

as n=m/Mr

Mr=mRT/PV

22
Q

Define a crystal lattice.

A

A crystal lattice is a regular repeating arrangement of ions. atoms or molecules in three dimensions.

23
Q

Define an ionic lattice.

A

Ionic lattices have three dimensional arrangements of alternating positive and negative ions.

24
Q

Describe the ionic lattices of sodium chloride and magnesium oxide.

A

They are cubic. LOOK AT DIAGRAM+READ NOTES.

25
Q

What are the physical properties of ionic crystals.

A

Strong and hard.
High melting and boiling which increase with charge density.
Do not conduct electricity in solid state ut in molten state.
Soluble in water because they form ion-dipole bond.

26
Q

Define a simple molecular structure.

A

Covalently bonded molecules have simple molecular structure. Simple molecular structure consist of a three dimensional arrangement of discrete molecules held together by weak intermolecular forces.

27
Q

Give three examples of substances with simple molecular structure.

A

Iodine
Ice
BuckminsterFullerene (buckyballs)

28
Q

Describe the structure of Iodine.

A

Iodine has simple molecular structure. It exists as a solid upto 30°c and sublimes above this temperature. When heated, the weak id-id forces are broken and individual I₂ molecules are set free as purple vapours. (SUBLIME).

29
Q

Describe the structure of ice.

A

Ice is a hydrogen bonded molecular solid. It has a three dimensional TETRAHEDRAL structure of ice (which resembles diamond)

30
Q

Explain why ice floats.

A

Ice floats because water expands on freezing. Therefore ice has less density than water and floats over water.

31
Q

What are Buckminster fullerenes?

A

Buckminster fullerenes C60 are allotropes of carbon. They have a shape of a football and consist of a regular pattern of hexagons and pentagons. They are relatively soft and have low melting and boiling point.

32
Q

Explain Buckminster fullerenes conductivity.

A

Buckminsterfullerene has low electrical conductivity as it has some delocalised electrons but to a lower extent.

33
Q

Is buckminsterfullerene soluble?

A

Buckminsterfullerene is slightly soluble in solvents such as carbon disulphide and methylbenzene.

34
Q

Is buckminsterfullerene reactive.

A

More reactive than graphite or diamond due to high electron density in certain part of molecule.

35
Q

Define what is meant by a fullerene.

A

Fullerenes are allotropes of carbon in the form of hollow spheres or tubes.

36
Q

Explain what is meant by a giant molecular lattice or macromolecular lattice.

A

Giant molecular lattices have a 3D network of covalent bonds throughout the whole structure.

37
Q

Which molecules have a giant molecular lattice.

A

Diamond, Graphite, silicon dioxide/silica or sand.

38
Q

Describe the structure of diamond.

A

In diamond the carbon atoms have sp3 hybridisation, with tetrahedral shape.
Diamond is the hardest known substance.

39
Q

Describe the properties of diamond.

A

Diamond has a high melting and boiling point and does not conduct electricity due to delocalised electrons.

40
Q

Describe the structure of silicon dioxide.

A

The structure of silicon dioxide resembles diamond(tetrahedral). Each si atom is bonded to 4 oxygen atoms but each O atom is bonded to only 2 silicon atoms. So the formula for silicon (IV) oxide is sio2.

41
Q

Describe the physical properties of silicon dioxide.

A

Silicon dioxide has similar physical properties to diamond.

42
Q

Define metallic bonding.

A

Metallic bonding is electrostatic force of attraction between positive metal ions and delocalised electrons. This attraction is very strong.

43
Q

Why are metals strong.

A

Metals are usually strong, not brittle. When a metal is hit, the layers of metal ions and are able to slide over each other and so the structure does not shatter.The metallic bonding do not break because the delocalised electrons are free to move through the structure. (this also explains why metals are malleable and ductile).

44
Q

Describe the structure of graphite.

A

In graphite the carbon atoms are arranged in hexagonal PLANAR layers. Between the layers, weak instantaneous dipole-dipole forces exist.

45
Q

Describe graphites conductivity.

A

Good conductor of electricity, although non-metal.

46
Q

Is graphite of soft or hard?

A

Graphite is relatively soft and easily scratched because the layers of carbon atoms are weak.

47
Q

Describe the melting and boiling points of graphite.

A

High melting and boiling points because of strong covalent bonding throughout the layers of carbon atoms.