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Organic chemistry > Special Reactions > Flashcards

Special Reactions Flashcards

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1
Q

Synthesize ether from alkyl halide

A

Williamson-ether synthesis

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2
Q

Forms alkyl benzene

A

Friedal-crafts alkylation

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3
Q

Forms keto benzene

A

Friedal-crafts acylation

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4
Q

What is Williamson Ether synthesis

A

Synthesize ether from alkylhalide

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5
Q

Forms alkenes using organophosphorus reagent

A

Witting reaction

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6
Q

Forms alkane from alkyl halide

A

Grignant reagent and organolithium compound

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7
Q

Yields alkene from amine

A

Hoffman elimination

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8
Q

Coupling reaction for alkane

A

Wurtz synthesis

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9
Q

Lengthens aldose by one

A

Killiani-Fischer synthesis

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10
Q

Formation of ester

A

Fisher esterification

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11
Q

Converts aldehyde to amino acid

A

Strecker synthesis

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12
Q

Gabriel synthesis

A

Preparation of 1* amine

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13
Q

Edman degradation

A

Technique to identify n-terminal amino acid

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14
Q

Memfield method

A

Automated peptide synthesis using an insoluble polymer

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15
Q

What is zaitsev rule

A

More substituted alkene is favored

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16
Q

Markonikov’s rule

A

H will bond to C with fewer alkyl substituent, X will bond to more alkyl substituent

Organic chemistry (4 decks)

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