solutions(henrys law) Flashcards
What is Henry’s law?
The mass of a gas dissolved in a given amount of a liquid at constant temperature is directly proportional to the pressure of gas present in equilibrium with the liquid
mαP, where m=KP
What do the variables m, P, and K represent in Henry’s law?
m = mass of the gas dissolved in a unit volume of the solvent, P = pressure of the gas in equilibrium with the solvent, K = Henry’s Constant
K is specific to each gas-solvent combination
What factors affect Henry’s law constant?
- The nature of the gas
- The nature of the solvent
- Temperature
- Pressure
These factors can influence the solubility of gases in liquids
Is Henry’s law applicable to ideal gases only?
Yes
It is not applicable to gases that undergo a chemical reaction
What are the conditions for a gas to be applicable under Henry’s law?
- The gas should be only slightly soluble in the liquid
- The gas should neither undergo association nor dissociation in the solvent
Ideal conditions for the law to hold true
Is Henry’s law valid for the solubility of HCl gas in water?
No
HCl is highly soluble in water, which violates the conditions for Henry’s law
What is the solubility behavior of NH3 in benzene according to Henry’s law?
Valid
NH3 is sparingly soluble in benzene, meeting the criteria of Henry’s law
Fill in the blank: Henry’s law states that the mass of a gas dissolved in a liquid is _______ to the pressure of the gas in equilibrium.
directly proportional
True or False: Henry’s law can be applied to gases that undergo a chemical reaction.
False
What happens to HCl and NH3 when dissolved in water?
HCl dissociates into H3O+ and Cl-, NH3 reacts with water to form NH4OH
These reactions indicate that these gases do not meet the criteria for Henry’s law in water