solutions(henrys law) Flashcards

1
Q

What is Henry’s law?

A

The mass of a gas dissolved in a given amount of a liquid at constant temperature is directly proportional to the pressure of gas present in equilibrium with the liquid

mαP, where m=KP

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2
Q

What do the variables m, P, and K represent in Henry’s law?

A

m = mass of the gas dissolved in a unit volume of the solvent, P = pressure of the gas in equilibrium with the solvent, K = Henry’s Constant

K is specific to each gas-solvent combination

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3
Q

What factors affect Henry’s law constant?

A
  • The nature of the gas
  • The nature of the solvent
  • Temperature
  • Pressure

These factors can influence the solubility of gases in liquids

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4
Q

Is Henry’s law applicable to ideal gases only?

A

Yes

It is not applicable to gases that undergo a chemical reaction

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5
Q

What are the conditions for a gas to be applicable under Henry’s law?

A
  • The gas should be only slightly soluble in the liquid
  • The gas should neither undergo association nor dissociation in the solvent

Ideal conditions for the law to hold true

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6
Q

Is Henry’s law valid for the solubility of HCl gas in water?

A

No

HCl is highly soluble in water, which violates the conditions for Henry’s law

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7
Q

What is the solubility behavior of NH3 in benzene according to Henry’s law?

A

Valid

NH3 is sparingly soluble in benzene, meeting the criteria of Henry’s law

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8
Q

Fill in the blank: Henry’s law states that the mass of a gas dissolved in a liquid is _______ to the pressure of the gas in equilibrium.

A

directly proportional

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9
Q

True or False: Henry’s law can be applied to gases that undergo a chemical reaction.

A

False

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10
Q

What happens to HCl and NH3 when dissolved in water?

A

HCl dissociates into H3O+ and Cl-, NH3 reacts with water to form NH4OH

These reactions indicate that these gases do not meet the criteria for Henry’s law in water

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