Solutions & Colligative Properties Flashcards
two components of a solution
solute
solvent
what is dissolved in sol’n
normally the component present in the smaller amount
solute
the dissolving medium
normally the component present in the larger amount
solvent
Equation: Molality (m)
m = moles solute / kilograms of solvent
Equation: Molarity (M)
M = moles solute / Liters of solution
concentration of 1 ppm means that every million grams of solution contain 1 g of solute
useful in expressing very low concentrations
parts per million (ppm)
occurs when solvent is added to a solution of high concentration to produce a solution of lower concentration
number of moles of solvent is conserved
dilution
Equation: Dilution
M(i) * V(i) = M(f) * V(f)
For aqueous solutions, ______ is governed by the present and concentration of ions in the solution. Movement of these ions in an electric field creates an __________
electrical conductivity
electric current
solutes whose solutions are conductive
electrolytes
An electrolyte is considered ______ if it dissociates completed into its component ions (Ex: ionic compounds NaCL and KI and molecular compounds with highly polar covalent bonds that dissociate into ions when dissolved, HCl in water)
strong
A __________ ionizes or hydrolyzes incompletely in aqueous solution and only some of the solute is present in ionic form
Ex: acetic acid and other weak acids, ammonia and other weak bases, and HgCl2
weak electrolyte
a compound that does not ionize at all in aqueous solution
retains molecular structure in solution
include many nonpolar gases and organic compounds (Oxygen and sugar)
nonelectrolytes
present of solute particles can make the physical properties of a sol’n different from those of the pure solvent
depends on the number of dissolved particles in the sol’n but not on their chemical identity or nature of the pure solvent
colligative property
pressure of the vapor above a fluid due to evaporated molecules
level of a liquid decreases with addition of a nonvolatile solute
vapor pressure