Gases Flashcards
force per unit area that the atoms or molecules exert on the walls of the container through collision
commonly expressed in units of atmospheres (1 atm) or millimeters of mercury (mmHg or torr)
Pressure (P)
SI Unit = Pascal (Pa) - 1 N / m^2, 1 atm = 760 mmHg = 760 torr
expressed in liters (L) or milliliters (mL)
Volume (V)
SI Unit = Liters (L) or milliliters (mL)
expressed as degrees Kelvin
T(K) = T(ºC) + 273 K
standard conditions for a gas
298 K (25ºC) 1 atm
standard temperature and pressure (STP)
273 K (0ºC) 1 atm
4 Assumptions made by the kinetic molecular theory of gases (for an ideal gas)
- Particles of a gas have no volume
- No intermolcecular attractions between gas particles
- Particles are in random motion, colliding elastically w/ one another and the walls of the cotainer
- Avg KE of the gas particles is proportional to the absolute temp and is the same for all gases at a given temp
For a given gaseous sample held at a constant temp (isothermal conditions), the volume of the gas is inversely proportional to its pressure
P1 * V1 = P2 * V2
*Boyle’s Law
For a given gaseous sample held at a constant pressure (isobaric conditions), the volume of a gas is directly proportional to its absolute temp
V1 / T1 = V2 / T2
*Charles’s Law
For a given gaseous sample held at a constant pressure and temp, the volume of a gas is directly proportional to the number of moles of gas present
n1 / V1 = n2 / V2
*Avogadro’s Law
Equation: Ideal Gas Law
*Combines information from the other 3 gas laws
PV = nRT
When we have a mixture of two or more gases in the same container, each exerts its own pressure known as _________
partial pressure
Equation: Mole Fraction of a gas A in a mixture of gases
X(A) = number of moles of A / total number of moles of gases
Equation: Partial pressure of a gas from its mole fraction
P(A) = P(t) * X(A)
Note: P(t) = total pressure of the system
Equation: Total pressure from partial pressure
P(t) = P1 + P2 + P3…..
*Equal to the sum of the partial pressures of the individual components
In a mixture of gases, each gas behaves ______ of the others, so the pressure that gas would exert would be the same as if it was in the container by itself
independently