Solubility and Distribution Flashcards

1
Q

Intrinsic
Altered only by chemical modification

A

Solubility

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2
Q

Extrinsic
Influenced by chemical, physical, or crystallographic means

A

Dissolution

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3
Q

Very Soluble (parts of solvent for one part of solute)

A

<1

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4
Q

The rate at which a molecule moves through a material is proportional to the concentration gradient, inversely proportional to the thickness of the membrane

A

Fick’s Law of Diffusion

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5
Q

Smaller particle size equates to

A

greater surface area and faster rate of dissolution

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6
Q

strong dipole effect and hydrogen bonding property; charges are separated permanently

A

polar solvents

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7
Q

strong dipole but do not have strong h-bonding activity

A

semipolar solvents

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8
Q

induce degree of polarity in a nonpolar solvent

A

semipolar solvents

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9
Q

It indicates the effect that a
substance has, when it acts as a medium, on the ease with
which two oppositely charged ions may be separated.

A

dielectric constant

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10
Q

epsilon = >50

A

polar solvents

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11
Q

epsilon = 20 - 50

A

semi - polar solvents

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12
Q

epsilon = 1 - 20

A

non - polar solvents

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13
Q

refers to the mutual solubilities of the components in a liquid-liquid system

A

miscibility

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14
Q

partial miscibility is affected by

A

temperature

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15
Q

substance is more soluble in higher temperatures

A

endothermic

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16
Q

Salts. very slightly soluble to slightly soluble

A

weak electrolytes

17
Q

salts of weak acids and bases

A

strong electrolytes

18
Q

pressure decreases, temperature increases

A

gas decreases

19
Q

pressure increases, temperature decreases

A

gas solubility increases

20
Q

The homogenous mixture of compounds which undergo melting at a lower temperature than that of the individual components.

A

Eutectic System

21
Q

solubility of weak electrolytes are strongly influenced by

A

pH of a solution

22
Q
A