Shapes of molecules and intermolecular forces Flashcards
What is the electron pair repulsion theory?
- The electron pairs surrounding a central atom determine the shape of the molecule
- The electron pairs repel one another so that they are arranged as far as possible
- The arrangement of electron pairs minimises repulsion
- Different number of electron pairs result in different shapes
What is bonding like in lone pairs?
- Repel more strongly than bonded pairs
- The bond angle is reduced by about 2.5 for each lone pair
How many bonding pairs are in a tetrahedral and what is the bond angle?
4 bonding pairs
109.5 degrees
How many bonding pairs are in a pyramidal and what is the bond angle?
3 bonding pairs and 1 lone pair
107 degrees
How many bonding pairs are in a non-linear shape and what is the bond angle?
2 bonding pairs and 2 lone pairs
104.5 degrees
How many bonding pairs are in a trigonal planar? and what is the bond angle?
3 bonding pairs
120 degrees
How many bonding pairs are in a octahedral and what is the bond angle?
6 bonding pairs
90 degrees
What shape is CO32- and NO3- and how many double bonds do they have?
Trigonal planar
1 double bond
What does it mean if a molecule is symmetrical?
Non polar
Why is non symmetrical molecule polar?
Because the dipoles do not cancel out
Why is non symmetrical molecule polar?
Because the dipoles do not cancel out