Foundations in Chemistry Flashcards
What is relative atomic mass?
Weighted mean mass of an atom compared to 1/12th mass of an atom of Carbon-12
What is relative isotopic mass?
Mass of an atom of an isotope compared with 1/12th mass of an atom of Carbon-12
What is the formula of an Ammonium ion?
NH4+
What is the formula of a carbonate ion?
CO3 2-
What is an ionic compound?
A compound made up of oppositely charged ions held together by electrostatic forces
What is the formula of a nitrate ion?
NO3-
What is the formula of a sulfate ion?
SO4 2-
What is atom economy?
A measure of the amount of starting materials that end up as useful products, a high atom economy means a process is more sustainable as there is less waste produced
What is the equation for atom economy?
% atom economy = Mr of desired products / Sum of Mr of all products * 100
What is avogadro’s constant?
Number of particles per mole of a substance (6.02*10^23)
What is a dative covalent bond?
A type of bond where both electrons in the shared pair come from the same atom
What is electronegativity?
The tendency of an atom to attract bonding electrons in a covalent bond
What is the mass of an electron?
1/1836
What is the mass number?
Number of protons and neutrons
What is one use of heavy water?
Used to control processes in nuclear reactors
What is a cation?
A positive ion, has fewer electrons than protons
How many particles are there in 1 mole?
6.02*10^23
What is empirical formula?
Simplest whole number ratio of atoms of each element in a compound
What is a method to determine the water of crystallisation in hydrated crystals?
- Weigh an empty crucible
- Add the hydrated salt into the weighed crucible, weigh crucible and hydrated salt
- Heat crucible, then heat strongly
- Leave crucible to cool, then weigh the anhydrous salt
What assumptions do you make when calculating water of crystallisation and what are solutions to these problems?
- All of the water has been lost, heat to constant mass
- No further decomposition, many salts decompose further when heated
What is a standard solution?
A solution of known concentration
How do you make up a standard solution?
Dissolving an exact mass of the solute in a solvent and making up the solution to an exact volume
What is the molar gas volume at RTP?
24 dm3
What is the ideal gas equation?
pV=nRT
How do you convert from dm3 to m3?
Divide by 1000
How do you convert from C to K?
+273
How do you experimentally find a relative molecular mass of a volatile liquid?
- Add a sample of the volatile liquid to a small syringe via a needle
- Inject the sample into a gas syringe
- Place gas syringe in a boiling water bath
What is the method to calculating reacting masses/quantities?
- Calculate the moles that reacts
- Write out the equations and calculate the amount of moles formed
- Calculate mass of product formed
What is the method for identifying an unknown metal?
- Weigh a sample of the metal and add to the flask
- Using a measuring cylinder, add HCl to the flask and add the bung
- Measure the max volume of gas in the syringe
What is the method to calculating the Mr of the unknown metal?
- From the experimental results the moles of H2 can be calculated
- From the equation use the moles of H2 to calculate moles of X
- Insert moles into mass/mr=mol equation
What is theoretical yield?
Assuming all of the reactants are converted into products
Why is it difficult to achieve maximum yield?
- The reaction may not have gone to completion
- Side reactions
- Purification of the product may result in loss of some product
What is the method to calculating percentage yield?
- Calculate the amount of moles of the element that reacts (theoretical yield)
- Use the equation to find the theoretical yield in moles
- Calculate the actual yield in moles
- Calculate the percentage yield
What is the limiting reagent?
The reactant that is not in excess (used up first and stops the reaction)
What is the atom economy of a chemical reaction?
A measure of how well atoms have been utilised
Why are reactions with high atom economies good?
- Produces a large proportion of desired products and few unwanted waste products
- Important for sustainability as they make the best use of natural resources
What is the method for calculating atom economy?
- Write the equation and the Mr of the products
- Calculate sum of desired products/sum of all products