Shapes of Molecules Flashcards
valance shell electron pair repulsion theory
shape depends on the number pf electrons around the central atom
each pair of electrons repel against other pairs so take up positions as far as apart as possible to minimise repulsion
do lone pairs or bond pairs have higher repulsion and why
lone pairs are higher in concentration so have greater repulsion as they are attracted to only one nucleus
how much does the angle decrease per lone pair
2.5 degrees
order of repulsion for lone pairs and bond pairs
lone pair-lone pair > lone pair-bond pair > bond pair-bond pair
shape and angle for:
2 bonding
0 lone
linear
180
shape and angle for:
3 bonding
0 lone
trigonal planar
120
shape and angle for:
2 bonding
1 lone
bent
118
shape and angle for:
4 bonding
0 lone
tetrahedral
109.5
shape and angle for:
3 bonding
1 lone
trigonal pyramid
107
shape and angle for:
2 bonding
2 lone
bent
104.5
shape and angle for:
5 bonding
0 lone
trigonal bipyramid
120 and 90
shape and angle for:
4 bonding
1 lone
see-saw
119 and 89
shape and angle for:
3 bonding
2 lone
trigonal planar 120
T-shape 89
shape and angle for:
6 bonding
0 lone
octahedral
90
shape and angle for:
5 bonding
1 lone
distorted square pyramid
89