Semiconductors and semiconductor devices Flashcards
What can carry charge? (2)
electrons in most solids
ions can also carry mostly in liquid solutions
Why don’t the negatively charged electron bump into the +ve charged Cu ions?
Because the electrons are waves travelling in a periodic arrangement of Cu ions - the electron wave avoids the ions – that’s partly the reason we
have an energy gap – the energy gap is related to the electron waves that can’t propagate because they are reflected by the planes of atoms – like Bragg reflection of X-rays
What happens in a microscopic model of conduction using Ohm’s law?
There will be defects which include dislocations, impurities, surfaces so the electrons accelerate for bit collide with a defect, stop or go off in a different direction and start again – this constant colliding is called scattering – the defect is called a scattering centre
• Even in a perfect crystal if T>0 the temperature induced motion moves the Cu ions from their usual position the crystal is not longer periodic and the electron is scattered
What is the defect called scattering centre
the electrons accelerate for bit collide with a defect, stop or go off in a different direction and start again – this constant colliding is called scattering
What is drift velocity?
the constant stop-go motion of the charge carrier (the electron) with an averaged velocity
How is conductivity determined in a metal?
determined by the concentration of electrons in the conduction band and the mobility of the electrons
How is mobility determined in a metal?
the mobility is determined by the number of scattering centres and the “effective mass” of the electron in the conduction band
In a metal, as As the temperature goes up……..scattering and mobility…
scattering goes up and the mobility drops.
If a metal has lots of dislocations the conductivity will be….
lower
What are the charge carriers in semiconductors?
the charge carriers are both electrons in the conduction band and holes in the valence band – the mobility the electrons and holes is usually different in a given semiconductor and also varies between semiconductors.
Conductivity in semiconductors increases when… temperature…..
The conductivity of semiconductors increases with temperature
Why does conductivity increase in semiconductors when temperature increases?
because although their mobility is reduced the concentration of electrons and holes increases and that dominates
When will charge carriers not scatter?
If we had a perfect crystal at T=0 then the charges carriers would not scatter and material would not obey Ohm’s law
What effects the mass of the charge carriers?
effected by moving through a period array of ions that make up the crystal lattice and to take account of that we say that the charge carrier has “an effective mass” in a solid. Electrons behave as if they had a different mass from free space when they are in a solid.
Apart from effective mass, what happens when you increase the number of defects and impurities in a solid?
increasing the number of defects and impurities in the solid reduces the mobility of the carriers and so reduces the conductivity.
Does the Presence of imperfections increase or decrease resistivity?
increases resistivity
What are examples of imperfections? (4)
grain boundaries dislocations
impurity atoms vacancies
Why do imperfections increase resistivity?
As they act to scatter electrons so that they take a less direct path