Science - Chemistry - Energy Changes - C5 Flashcards
if the products of a reaction store more energy than the original reactants, where was the energy transferred from ?
the surroundings
if the products of a reaction stores less energy than the original reactants, where was the excess energy transferred to ?
the surroundings
how is energy usually transferred between the reactants and the surroundings during a chemical reaction ?
by heating
if energy is transferred to the surroundings, what will happen to the temperature of the surroundings ?
it will increase
if energy is transferred from the surroundings, what will happen to the temperature of the surroundings ?
it will decrease
why doesn’t the amount of energy in the reactants and surroundings change ?
the conservation of energy - energy can’t be created nor destroyed, only transferred
what is an exothermic reaction ?
a reaction where energy is transferred from the reaction to the surroundings
how is an exothermic reaction shown ?
by a temperature increase in the reactions
give an example of an exothermic reaction
combustion - burning fuels
what is an everyday use of an exothermic reaction ?
- hand warmers use exothermic reactions
what is an endothermic reaction ?
a reaction where energy is taken in from the surroundings during a reaction
how is an endothermic reaction shown ?
a decrease in temperature in the surroundings
what is an example of an endothermic reaction ?
photosynthesis
which type of reaction is more common - endothermic or exothermic ?
exothermic
what is an everyday use of an endothermic reaction ?
a sports injury pack is a cold pack used to reduce swelling, they take in heat and the pack becomes cold
how can you compare how energy transfer changes ?
by measuring the temperature change of a reaction under different conditions
what is the amount of energy transferred during a reaction proportional to ?
the temperature change of that reaction
describe the experiment on how to measure energy transfer of reactions ?
- take the temperature of the reactants, mixing everything together in a polystyrene cup
- measure the temperature
- seal the cup as much as possible, put cotton around the cup to insulate it and stop energy being lost to the surroundings
- measure the temperature at the end of the reaction
what is the hardest thing when doing the experiment to measure energy transfer of reactions ?
the amount of energy that’s lost to the surroundings during the experiment
why does a polystyrene cup help with the experiment energy transfer of reactions ?
it helps to insulate the reaction mixture more than a glass beaker
what does the energy transfer of reactions experiment method work for ?
reactions of solids with liquids
reactions where you mix 2 solutions
how can you vary the energy transfer of reactions experiment ?
- you can investigate the effect of changing the amount of reactant has on the energy transferred, so you can repeat the experiment with a different mass/ concentration
if the reaction is exothermic, the bigger the
temperature of the solution will increase
the more energy is released, the
bigger the increase in temperature will be
if the reaction is endothermic the energy will be
absorbed and the temperature of the solution will decrease
the more energy absorbed, the bigger the
the decrease in temperature will be
what is energy measured in ?
joules
what are large energy values given in ?
kilojoules
how many joules are there in a kilojoule ?
1000
what does the amount of energy released or absorbed depend on ?
how much a reactant is used
what is energy transfer usually measured in ?
kilojoules per mole of reactant
why is energy transferred in chemical reactions ?
because old bonds are broken and new bonds are formed
what type of process is breaking a bond ?
an endothermic process
why is breaking bonds an endothermic process ?
energy must be supplied to break existing bonds
what type of process is making a bond ?
exothermic
why is making a bond an exothermic process ?
energy is released when new bonds are formed
what does a reaction being exothermic or endothermic depend on ?
- what bond breaking and what bond making is going on
- whether the amount of energy is absorbed when the bonds in the reactants are broken is more or less
- when the bonds in the products are made
what happens with energy and bonds in an exothermic reaction ?
- the energy released in bond formation is greater than the energy used in breaking old bonds
- the leftover energy is released into the surroundings and the temperature rises
what happens with energy and bonds in an endothermic reaction ?
- the energy needed to break old bonds is greater than the energy released when new bonds are formed
- the extra energy needed is absorbed from the surroundings and the temperature falls
why do some bonds need more energy to break than others ?
each chemical bond has a particular bond energy associated with it
what formula is used to work out the overall charge ?
energy change = energy of bond breaking - energy of bond making
if the overall energy change is negative what does that show ?
more energy was released in bond making than used in bond breaking - exothermic
if the overall energy change is positive what does that show ?
more energy was used in bond breaking than bond making - endothermic
what is a cell ?
a system that contains chemicals which react and produce electricity
what does a cell contain ?
2 different electrodes in contact with an electrolyte
what do the 2 electrodes in a cell must be able to do ?
conduct electricity
what are electrodes usually made of because they need to conduct electricity ?
metals
what is an electrolyte ?
a liquid hat conducts electricity and contains ions which react with the electrodes
what do the chemical reactions between the electrodes and the electrolyte do ?
set up a charge difference between the electrodes
how is electricity produced in a circuit ?
electrodes are connected by a wire then charge can flow
what is the charge difference ?
the voltage of the cell
what causes charge difference ?
different metals react differently with the same electrolyte
the bigger the difference in reactivity of electrodes, the
bigger the voltage of the cell
if theres no difference in reactivity because the reactivity of the metals is the same or the same metal is used as an electrode, what will the voltage of the cell be ?
0
what does the voltage of the cell depend on ?
the concentration of ions in the electrolyte
why does the concentration of ions in the electrolyte affect the voltage of a cell ?
as the ions in the electrolyte react, their concentration will decrease, so will the voltage of the cell so the cell will drop to 0 and stop working
what is a battery ?
2 or more cells connected together
why is the voltage of the battery greater than
any of the individual cells in the battery ?
the voltage of the battery is all the voltages of the cell added together
how are some cells non - rechargeable ?
the chemical reactions that happen in the electrodes are irreversible because over time the reacting particles get used up and turn into the products of the reaction once any of the reactants are used up, the cell won’t work
how does a rechargeable cell work ?
the reaction can be reversed by connecting it to an external electric current
what is a fuel cell ?
an electrical cell that’s supplied with a fuel and oxygen and efficiently transfers the energy released by the reaction between them as electricity
how do fuel cells work ?
- the fuel enters the cell at one side
- it becomes oxidised and sets up a potential difference within a cell
- potential difference powers the device that the fuel is connected to
- oxygen enters the the cell at the other side, where it reacts to form water
what is a hydrogen - oxygen fuel cell ?
the fuel cell is hydrogen which is oxidised when it combines with oxygen to produce water and releases energy
what is the electrolyte a solution of in hydrogen - oxygen fuel cells ?
potassium hydroxide
what are the electrodes in hydrogen - oxygen fuel cells ?
porous carbon with a catalyst
what happens at the negative electrode during hydrogen-oxygen fuel cells ?
hydrogen loses the electrons to produce H+ ions - oxidation
what happens at the positive electrode during hydrogen-oxygen fuel cells ?
oxygen gains electrons and reacts with H+ ions to make water - reduction
what type of reaction is the hydrogen-fuel cell ?
a redox reaction where hydrogen and oxygen react to make water
what are advantages to hydrogen fuel cells and batteries ?
- don’t produce as much pollution
- batteries are rechargeable
- batteries store less energy than fuel cells
what are disadvantages of hydrogen fuel cells ?
- hydrogen is a gas so takes up more space to store
- batteries are or expensive than fuel cells
- hydrogen is explosive when mixed with air so is more hard to store safely
- hydrogen fuel is made from hydrocarbons or by electrolysis of water which uses electricity and this has to be generated somehow