S13-S15 Flashcards
WHAT IS GREEN CHEMISTRY?
This innovative approach to the synthesis of new chemicals seeks environmental sustainability in order to make chemistry healthier and more environmentally friendly.
What is environmental pollution?
Environmental pollution is the negative impact of changes in the environment on plants, animals, and humans. A chemical that creates pollution is called a pollutant. Pollutants, which can be solid, liquid, or gaseous chemicals, manifest in higher concentrations than natural abundance due to human or natural causes.
In the process of environmental pollution, pollutants originate from a source and get transported by air or water or are dumped into the soil by human beings.
Go greener by…
Environmental Sustainability
Reduced Derivatives
Design for Degradation
Real-time Pollution Prevention
Safer Chemistry for Accident Protection
The Three Pillars of Sustainability
The social pillar of sustainability is focused on ensuring all members of society have fair access to resources and opportunities.
The economic pillar of sustainability involves supporting the economic growth and financial stability of communities and individuals, without compromising their social, environmental, and cultural values.
The environmental pillar of sustainability involves keeping the natural environment healthy, protected, and restored (if necessary).
How to integrate environmental sustainability into today’s world
Restore and protect the environment
Make simple swaps
Invest in new technology
Change our perspective
Examples of Environmental sustainability
Sustainable agriculture
Sustainable forestry
Sustainable construction
Renewable energy sources
Sustainability benefits
Sustainability has benefits for the entire world with reductions in carbon footprints and the amount of toxins and pollutants released into the environment. As we see the effects of climate change taking hold, it is more important than ever to seek sustainable solutions, not only to create a cleaner and healthier world, but also to potentially prevent catastrophic changes to the environment in the future.
What is a catalyst
A catalyst is a substance that increases the rate of a reaction leading to the product(s), whereby the catalyst does not undergo any chemical change.
A catalyst speeds up a reaction by providing new pathways (elementary steps) with more favorable reaction kinetics than those that exist in the uncatalyzed reaction.
Lowered energy requirements are a basic part of the practice of green chemistry and in this respect highly efficient catalysts can be extremely beneficial in reducing energy consumption and in so doing lowering costs and environmental impact.
The most common benefits of catalysis
Sustainability and green chemistry
Improved efficiency
Reduced waste and pollution
Versatility and specificity
Cost-effectiveness
What does degradation mean in chemistry?
Degradation is simply the breakdown of substances (materials) into simpler constituent substances. Organic molecules usually degrade in several stages, starting with the removal of a functional group.
Biodegradable Plastics
this type of plastics can be substituted for plastics that are non-degradable to minimize the stress from the dwindling availability of landfill sites and plastic pollution. Also, the application of biodegradable plastics can decrease greenhouse gas emissions in the course of usage.
Examples:
Starch-based plastics
Soy-based plastics
Cellulose-based plastics
Lignin-based plastics
Chemical Degradation
some chemicals degrade in several ways, depending on their composition and molecular structure.
Heat - at certain temperatures, some chemicals (particularly organic ones) can become unstable and start to break down.
Acid and Bases - strong inorganic acid and bases act as catalysts and can easily break down organic compounds.
Sunlight - some organic compounds undergo photodegradation as a result of ionizing radiation from the sun’s UV rays
Enzymes - organic tissues start to decompose when they die.
Bacteria and Fungi - the decomposition of organic tissues is mainly facilitated by decomposers.
Water or Moisture - many organic substances either dissolve easily in water or degrade when they absorb moisture.
Oxygen - some organic compounds, especially medicines, are sensitive to oxygen. These compounds can be easily oxidized when they’re exposed to air.
How is degradation related to sustainable chemistry?
Degradation can help to achieve the goals of sustainable chemistry by eliminating – or at least reducing – the impact of chemical products in the environment
What is real-time analysis
It is a process where data is collected and analyzed in real-time to monitor and detect changes in pollution levels.
Examples:
sensors
monitors
analytical techniques
Safer Chemistry for Accident Protection
Chemicals and their phase (solid, liquid, or gas) should be selected so as to minimize the potential for chemical accidents (including explosions, fires, and releases to the environment).
According to the ‘‘Chemical accident prevention and the clean air act amendments of 1990,’’ preventing accidents starts by identifying and assessing the hazards.
How to Control the Risk of Hazardous Chemicals
Hierarchy of controls:
Elimination - physically remove the hazard
Substitution - replace the hazard
Engineering Controls - isolate people from the hazard
Administrative Controls - change the way people work
PPE - protect the worker with PPE
Benefits of Green Chemistry in the Environment
Many chemicals end up in the environment by intentional release during use (e.g., pesticides), by unintended releases (including emissions during manufacturing), or by disposal. Green chemicals either degrade to innocuous products or are recovered for further use.
Plants and animals suffer less harm from toxic chemicals in the environment.
Lower potential for global warming, ozone depletion, and smog formation.
Less chemical disruption of ecosystems.
Less use of landfills, especially hazardous waste landfills.
What is TOXICOLOGY
toxicos - “poisonous”
logos - “subject matter”
Toxicant
is a substance that has a deleterious effect on living organisms. It may be a discrete toxic chemical (e.g., lead chromate) or a mixture of toxic chemicals (e.g., gasoline).
Toxin
is a specific protein produced by living organisms (e.g., mushroom toxin or tetanus toxin)
Poison
is a toxicant that causes immediate death or illness when experienced in very small amounts
What is environmental toxicology
is a multidisciplinary science that studies the deleterious repercussions of diverse chemical, biological, and physical agents on living organisms.
FACTORS THAT AFFECT THE TOXICITY OF CHEMICAL SUBSTANCES
- Structure and innate chemical activities
- Dosage
- Susceptibility of Organisms (ex. Age and Sex)
- Dose-response relationship
- Dose-time relationship or exposure
- Species differentiation
- Route of Exposure
- Toxicokinetics
- Interactions due to the presence of other chemicals
Structure of Chemical Substances
- structural isomers
- stereoisomers
- oxidation state
Chemical Activity of Substance
- Some can quickly damage the cells causing their immediate death.
- Others slowly interfere with a specific cell function.
Dosage
-the amount of a particular toxic agent to which a body is exposed (administered dose)
Susceptibility of Organisms
-age, sex, diet, health status, genetics, prior exposure to the agent, and exposures to other agents
Dose-response relationship
-shows how the amount of a substance you’re exposed to relates to the harm it can cause - the more you’re exposed to, the greater the potential for harm
DOSE-TIME RELATIONSHIP OR EXPOSURE
-the period over which a dose is administered
Acute (1 day)
Subacute (10 days)
Subchronic (2 weeks to 7 years)
Chronic (7 years to a lifetime)