RXNS Flashcards

1
Q

HYDROHALOGENATION

A
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2
Q

HYRDROHALOGENATION (WITH REARRANGMEMENT)

A
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3
Q

HALOGENATION

A
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4
Q

HYDROBROMINATION WITH PEROXIDE

A
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5
Q

HYDRATION

A
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6
Q

HYDRATION WITH REARRANGEMENT

A
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7
Q

BROMINATION IN H20

A
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8
Q

OXYMERCURATION - DEMERCURATION

A
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9
Q

HYDROBORATION-OXIDATION

A
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10
Q

SYN DYHYDROXYLATION

A
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11
Q

SYN DYHYDROXYLATION

A
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12
Q

ANTI-DIHYDROXYLATION

A
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13
Q

ADDITION OF AN ALCOHOL

A
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14
Q

BROMINATION IN ALCOHOL

A
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15
Q

ALKOXYMERCURATION- DEMERCURATION

A
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16
Q

EPOXIDATION

A
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17
Q

CATALYTIC HYDROGENATION

A
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18
Q

OZONOLYSIS (REDUCING CONDITIONS)

A
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19
Q

OZONOLYSIS (OXIDIZING CONDITIONS/ OXIDATIVE CLEAVAGE)

A
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20
Q

CATALYTIC HYDROGENATION (CATALYTIC REDUCTION)

A
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21
Q

REDUCTION TO CIS-ALKENE

A
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22
Q

REDUCTION TO TRANS-ALKENE

A
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23
Q

HYDROHALOGENATION WITH HBR (TERMINAL ALKYNE)

A
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24
Q

HYDROHALOGENATION WITH HBR ( INTERNAL ALYKYNE)

A
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25
Q

HALOGENATION WITH BR2

A
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26
Q

HYDRATION OF AN INTERNAL ALKYNE

A
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27
Q

HYDRATION OF A TERMINAL ALKYNE ( MARKOVNIKOV)

A
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28
Q

HYDRATION OF A TERMINAL ALKYNE ( ANTI-MARKOVNIKOV)

A
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29
Q

SN2 ADDITION OF AN ACETYLIDE ION TO AN ALYKL HALIDE

A
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30
Q

SN2 ADDITION OF ACETYLIDE ION TO A KETONE

A
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31
Q

SN2 ADDITION OF AN ACETYLIDE ION TO AN EPOXIDE

A
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32
Q

OZONOLYSIS/OXIDATIVE CLEAVAGE OF AN INTERNAL ALKYNE

A
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33
Q

OZONOLYSIS/OXIDATIVE CLEAVAGE OF A TERMINAL ALKYNE

A
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34
Q

ALYKNE FORMATION FROM DOUBLE ELIMINATION OF A VICINAL DIHALIDE

A
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35
Q

FREE RADICAL HALOGENATION USING BROMINE (MORE SELECTIVE)

A
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36
Q

FREE RADICAL HALOGENATION USING CHLORIDE (LESS SELECTIVE)

A
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37
Q

ACYLIC/BENZYLIC BROMINATION

A
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38
Q

DIENE ADDITION TO AN DIENOPHILE (ALKENE)

A
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39
Q

DIENE ADDITION TO A DIENOPHILE (ALKYNE)

A
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40
Q

DIENE ADDITION TO A CIS DIENOPHILE

A
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41
Q

DIENOPHILE TO A TRANS DIENOPHILE

A
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42
Q

DIENE ADDITION TOA SUBSTITUTED DIENOPHILE

A
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43
Q

ADDITION OF A GRIGNARD REAGENT TO AN ALDEHYDE

A
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44
Q

ADDITION OF A GRIGNARD REAGENT TO AN KETONE

A
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45
Q

ADDITION OF A GRIGNARD REAGENT TO AN ESTER

A
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46
Q

ADDITION OF A GRIGNARD REAGENT TO AN ACYL CHLORIDE

A
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47
Q

ADDITION OF A GRIGNARD REAGENT TO CO2

A
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48
Q

ADDITION OF A GRIGNARD REAGENT TO AN EXPOXIDE ( ADDS TO THE LESS SUBS. SIDE)

A
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49
Q

ADDITION OF A GRIGNARD REAGENT TO A CARBOXYLIC ACID

A
50
Q

ADDITION OF A GRIGNARD REAGENT TO AN AMIDE

A
51
Q

ADDITION OF A GRIGNARD REAGENT TO A NITRILE

A
52
Q

FRIEDEL CRAFTS ALKYLATION ( REARRANGEMENT POSSIBLE)

A
53
Q

FRIEDEL CRAFTS ALKYLATION (NO REARRANGEMENT POSSIBLE)

A
54
Q

BROMINATION

A
55
Q

CHLORINATION

A
56
Q

NITRATION

A
57
Q

SULFONATION

A
58
Q

FORMYLATION

A
59
Q

EAS WITH AN ORTHO/PARA DIRECTING GROUP ON BENZENE

A
60
Q

EAS META-DIRECTING GROUP ON BENZENE

A
61
Q

FRIEDEL-CRAFTS ALKYLATION/ACYLATION WITH A META-DIRECTING GROUP OR AN AMINE ON BENZENE

A
62
Q

SIDE CHAIN OXIDATION OF BENZENE TO FORM BENZOIC ACID

A
63
Q

SIDE CHAIN OXIDATION OF BENZENE TO FORM BENZOIC ACID

A
64
Q

WOLF-KISHNER REDUCTION

A
65
Q

CLEMMENSEN REDUCTION

A
66
Q

ACETYLATION OF ANALINE USING ACETIC ANHYDRIDE

A
67
Q

DIAZONIUM SALT REACTIONS

A
68
Q

DIAZONIUM SALT REACTIONS

A
69
Q

REDUCTION OF AN ALDEHYDE TO A 1 ALCOHOL

A
70
Q

REDUCTION OF A KETONE TO A 2 ALCOHOL

A
71
Q

REDUCtION OF A CARBOXYLIC acid to a 1 alcohol

A
72
Q

REDUCTION OF AN ESTER TO AN 1 ALCOHOL

A
73
Q

REDUCTION OF AN ESTER TO AN ALDEHYDE

A
74
Q

REDUCTION OF AN ACYL CHLORIDE TO A 1 ALCOHOL

A
75
Q

REDUCTION OF AN ACYL CHLORIDE TO A 1 ALCOHOL

A
76
Q

REDUCTION OF AN AMIDE TO AN AMINE

A
77
Q

REDUCTION OF AN ACYL CHLORIDE TO AN ALDEHYDE

A
78
Q

HOFMANN REARRANGEMENT

A
79
Q

REDUCTION OF A NITRILE TO AN AMINE

A
80
Q

CONVERSION OF A 2/3 ALCOHOL TO AN ALKYL HALIDE VIA SN1

A
81
Q

CONVERSION OF A 1/2 ALCOHOL TO AN ALKYL BROMIDE VIA SN2

A
82
Q

CONVERSION OF A 1/2 ALCOHOL TO AN ALKYL CHLORIDE VIA SN2

A
83
Q

CONVERSION OF AN ALCOHOL TO A TOSYLATE ESTER (OTS)

A
84
Q

ACID CATALYZED DEHYDRATION OF AN ALCOHOL

A
85
Q

CHROMIC ACID OXIDATION OF A 1 ALCOHOL TO A CARBOXYLIC ACID

A
86
Q

CHROMIC ACID OXIDATION OF A 2 ALCOHOL TO A KETONE

A
87
Q

Chromic Acid Oxidation of an Aldehyde to a
Carboxylic Acid

A
88
Q

PCC or DMP Oxidation of a 1
Alcohol to an Aldehyde

A
89
Q

PCC or DMP Oxidation of a 2
Alcohol to a Ketone

A
90
Q

Oxidative Cleavage of a 1,2 Diol

A
91
Q

Swern Oxidation

A
92
Q

Williamson Ether Synthesis via SN2

A
93
Q

Acid-catalyzed Cleavage of Ethers when
one side is 2 ̊/3 ̊ (Nucleophile attacks more substituted side via SN1)

A
94
Q

ACID CATALYZED CLEAVAGE OF ETHERS WHEN NEITHER SIDE IS 2/3 (NUCLEOPHILE ATTACKS LESS SUB. SIDE VIA SN2)

A
95
Q

ACID CATALYZED RING OPENING OF EPOXIDES (NUCLEOPHILE ATTACKS MORE SUB. SIDE)

A
96
Q

BASE CATALYZED RING OPENING OF EPOXIDES (NUCLEOPHIOLE ATTACKS LESS SUB. SIDE)

A
97
Q

NUCLEOPHILIC ADDITION TO AN ALDEHYDE OR KETONE

A
98
Q

ADDITION OF WATER TO AN ALDEHYDE OR KETONE FORMING A HYDRATE

A
99
Q

BASE CATALYZED ADDITION OF AN ALCOHOL TO AN ALDEHYDE OR KETONE FORMING A HEMI-ACETAL/HEMI-KETAL

A
100
Q

ACID CATALYZED ADDITION OF AN ALCOHOL TO AN ALDEHYDE OR KETONE FORMING A ACTETAL/KETAL (PROTECTING GROUP, REVERSED BY H30)

A
101
Q

ACID CATALYZED ADDITION OF ETHYLENE GLYCOL TO AN ALDEHYDE OR KETONE FORMING ACETAL/KETAL (PROTECTING GROUP, REVERSED BY H30)

A
102
Q

ADDITION OF A 1 AMINE TO AN ALDEHYDE OR KETONE FORMING AN IMINE ( REVERSED BY H30)

A
103
Q

Addition of a 2 ̊ Amine to an Aldehyde or Ketone forming an Enamine (Reversed by H3O
+)

A
104
Q

ADDITION OF A WITTIG REAGENT TO AN ALDEHYDE/KETONE

A
105
Q

Michael Addition to an α, β Unsaturated
Ketone

A
106
Q

Michael Addition to an α, β Unsaturated
Ketone with a Gilman Reagent
(Organocuprates)

A
107
Q

Acid-catalyzed Hydrolysis of a Nitrile

A
108
Q

SN2 formation of Nitriles using Cyanide
and Alkyl Halides

A
109
Q

Cyanohydrin Formation using
Aldehydes/Ketones and Cyanide

A
110
Q

Carboxylic Acid Derivative Reactions

A
111
Q

Self Aldol
Condensation
and Enone
Formation

A
112
Q

Mixed Aldol
Condensation
and Enone
Formation

A
113
Q

Self Claisen
Condensation

A
114
Q

Mixed Claisen
Condensation

A
115
Q

Dieckmann
Cyclization
(Intramolecular
Claisen
Condensation)

A
116
Q

Acetoacetic
Ester Synthesis

A
117
Q

Malonic Ester
Synthesis

A
118
Q

Alpha
Halogenation
In Basic
Conditions

A
119
Q

Alpha
Halogenation in
Acidic
Conditions

A
120
Q

Haloform
Reaction

A