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ORGANIC CHEMISTRY > RXNS > Flashcards

RXNS Flashcards

1
Q

HYDROHALOGENATION

A
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2
Q

HYRDROHALOGENATION (WITH REARRANGMEMENT)

A
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3
Q

HALOGENATION

A
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4
Q

HYDROBROMINATION WITH PEROXIDE

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5
Q

HYDRATION

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6
Q

HYDRATION WITH REARRANGEMENT

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7
Q

BROMINATION IN H20

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8
Q

OXYMERCURATION - DEMERCURATION

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9
Q

HYDROBORATION-OXIDATION

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10
Q

SYN DYHYDROXYLATION

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11
Q

SYN DYHYDROXYLATION

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12
Q

ANTI-DIHYDROXYLATION

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13
Q

ADDITION OF AN ALCOHOL

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14
Q

BROMINATION IN ALCOHOL

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15
Q

ALKOXYMERCURATION- DEMERCURATION

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16
Q

EPOXIDATION

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17
Q

CATALYTIC HYDROGENATION

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18
Q

OZONOLYSIS (REDUCING CONDITIONS)

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19
Q

OZONOLYSIS (OXIDIZING CONDITIONS/ OXIDATIVE CLEAVAGE)

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20
Q

CATALYTIC HYDROGENATION (CATALYTIC REDUCTION)

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21
Q

REDUCTION TO CIS-ALKENE

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22
Q

REDUCTION TO TRANS-ALKENE

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23
Q

HYDROHALOGENATION WITH HBR (TERMINAL ALKYNE)

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24
Q

HYDROHALOGENATION WITH HBR ( INTERNAL ALYKYNE)

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25
Q

HALOGENATION WITH BR2

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26
Q

HYDRATION OF AN INTERNAL ALKYNE

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27
Q

HYDRATION OF A TERMINAL ALKYNE ( MARKOVNIKOV)

A
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28
Q

HYDRATION OF A TERMINAL ALKYNE ( ANTI-MARKOVNIKOV)

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29
Q

SN2 ADDITION OF AN ACETYLIDE ION TO AN ALYKL HALIDE

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30
Q

SN2 ADDITION OF ACETYLIDE ION TO A KETONE

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31
Q

SN2 ADDITION OF AN ACETYLIDE ION TO AN EPOXIDE

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32
Q

OZONOLYSIS/OXIDATIVE CLEAVAGE OF AN INTERNAL ALKYNE

A
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33
Q

OZONOLYSIS/OXIDATIVE CLEAVAGE OF A TERMINAL ALKYNE

A
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34
Q

ALYKNE FORMATION FROM DOUBLE ELIMINATION OF A VICINAL DIHALIDE

A
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35
Q

FREE RADICAL HALOGENATION USING BROMINE (MORE SELECTIVE)

A
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36
Q

FREE RADICAL HALOGENATION USING CHLORIDE (LESS SELECTIVE)

A
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37
Q

ACYLIC/BENZYLIC BROMINATION

A
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38
Q

DIENE ADDITION TO AN DIENOPHILE (ALKENE)

A
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39
Q

DIENE ADDITION TO A DIENOPHILE (ALKYNE)

A
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40
Q

DIENE ADDITION TO A CIS DIENOPHILE

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41
Q

DIENOPHILE TO A TRANS DIENOPHILE

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42
Q

DIENE ADDITION TOA SUBSTITUTED DIENOPHILE

A
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43
Q

ADDITION OF A GRIGNARD REAGENT TO AN ALDEHYDE

A
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44
Q

ADDITION OF A GRIGNARD REAGENT TO AN KETONE

A
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45
Q

ADDITION OF A GRIGNARD REAGENT TO AN ESTER

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46
Q

ADDITION OF A GRIGNARD REAGENT TO AN ACYL CHLORIDE

A
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47
Q

ADDITION OF A GRIGNARD REAGENT TO CO2

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48
Q

ADDITION OF A GRIGNARD REAGENT TO AN EXPOXIDE ( ADDS TO THE LESS SUBS. SIDE)

A
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49
Q

ADDITION OF A GRIGNARD REAGENT TO A CARBOXYLIC ACID

50
Q

ADDITION OF A GRIGNARD REAGENT TO AN AMIDE

51
Q

ADDITION OF A GRIGNARD REAGENT TO A NITRILE

52
Q

FRIEDEL CRAFTS ALKYLATION ( REARRANGEMENT POSSIBLE)

53
Q

FRIEDEL CRAFTS ALKYLATION (NO REARRANGEMENT POSSIBLE)

54
Q

BROMINATION

55
Q

CHLORINATION

56
Q

NITRATION

57
Q

SULFONATION

58
Q

FORMYLATION

59
Q

EAS WITH AN ORTHO/PARA DIRECTING GROUP ON BENZENE

60
Q

EAS META-DIRECTING GROUP ON BENZENE

61
Q

FRIEDEL-CRAFTS ALKYLATION/ACYLATION WITH A META-DIRECTING GROUP OR AN AMINE ON BENZENE

62
Q

SIDE CHAIN OXIDATION OF BENZENE TO FORM BENZOIC ACID

63
Q

SIDE CHAIN OXIDATION OF BENZENE TO FORM BENZOIC ACID

64
Q

WOLF-KISHNER REDUCTION

65
Q

CLEMMENSEN REDUCTION

66
Q

ACETYLATION OF ANALINE USING ACETIC ANHYDRIDE

67
Q

DIAZONIUM SALT REACTIONS

68
Q

DIAZONIUM SALT REACTIONS

69
Q

REDUCTION OF AN ALDEHYDE TO A 1 ALCOHOL

70
Q

REDUCTION OF A KETONE TO A 2 ALCOHOL

71
Q

REDUCtION OF A CARBOXYLIC acid to a 1 alcohol

72
Q

REDUCTION OF AN ESTER TO AN 1 ALCOHOL

73
Q

REDUCTION OF AN ESTER TO AN ALDEHYDE

74
Q

REDUCTION OF AN ACYL CHLORIDE TO A 1 ALCOHOL

75
Q

REDUCTION OF AN ACYL CHLORIDE TO A 1 ALCOHOL

76
Q

REDUCTION OF AN AMIDE TO AN AMINE

77
Q

REDUCTION OF AN ACYL CHLORIDE TO AN ALDEHYDE

78
Q

HOFMANN REARRANGEMENT

79
Q

REDUCTION OF A NITRILE TO AN AMINE

80
Q

CONVERSION OF A 2/3 ALCOHOL TO AN ALKYL HALIDE VIA SN1

81
Q

CONVERSION OF A 1/2 ALCOHOL TO AN ALKYL BROMIDE VIA SN2

82
Q

CONVERSION OF A 1/2 ALCOHOL TO AN ALKYL CHLORIDE VIA SN2

83
Q

CONVERSION OF AN ALCOHOL TO A TOSYLATE ESTER (OTS)

84
Q

ACID CATALYZED DEHYDRATION OF AN ALCOHOL

85
Q

CHROMIC ACID OXIDATION OF A 1 ALCOHOL TO A CARBOXYLIC ACID

86
Q

CHROMIC ACID OXIDATION OF A 2 ALCOHOL TO A KETONE

87
Q

Chromic Acid Oxidation of an Aldehyde to a
Carboxylic Acid

88
Q

PCC or DMP Oxidation of a 1
Alcohol to an Aldehyde

89
Q

PCC or DMP Oxidation of a 2
Alcohol to a Ketone

90
Q

Oxidative Cleavage of a 1,2 Diol

91
Q

Swern Oxidation

92
Q

Williamson Ether Synthesis via SN2

93
Q

Acid-catalyzed Cleavage of Ethers when
one side is 2 ̊/3 ̊ (Nucleophile attacks more substituted side via SN1)

94
Q

ACID CATALYZED CLEAVAGE OF ETHERS WHEN NEITHER SIDE IS 2/3 (NUCLEOPHILE ATTACKS LESS SUB. SIDE VIA SN2)

95
Q

ACID CATALYZED RING OPENING OF EPOXIDES (NUCLEOPHILE ATTACKS MORE SUB. SIDE)

96
Q

BASE CATALYZED RING OPENING OF EPOXIDES (NUCLEOPHIOLE ATTACKS LESS SUB. SIDE)

97
Q

NUCLEOPHILIC ADDITION TO AN ALDEHYDE OR KETONE

98
Q

ADDITION OF WATER TO AN ALDEHYDE OR KETONE FORMING A HYDRATE

99
Q

BASE CATALYZED ADDITION OF AN ALCOHOL TO AN ALDEHYDE OR KETONE FORMING A HEMI-ACETAL/HEMI-KETAL

100
Q

ACID CATALYZED ADDITION OF AN ALCOHOL TO AN ALDEHYDE OR KETONE FORMING A ACTETAL/KETAL (PROTECTING GROUP, REVERSED BY H30)

101
Q

ACID CATALYZED ADDITION OF ETHYLENE GLYCOL TO AN ALDEHYDE OR KETONE FORMING ACETAL/KETAL (PROTECTING GROUP, REVERSED BY H30)

102
Q

ADDITION OF A 1 AMINE TO AN ALDEHYDE OR KETONE FORMING AN IMINE ( REVERSED BY H30)

103
Q

Addition of a 2 ̊ Amine to an Aldehyde or Ketone forming an Enamine (Reversed by H3O
+)

104
Q

ADDITION OF A WITTIG REAGENT TO AN ALDEHYDE/KETONE

105
Q

Michael Addition to an α, β Unsaturated
Ketone

106
Q

Michael Addition to an α, β Unsaturated
Ketone with a Gilman Reagent
(Organocuprates)

107
Q

Acid-catalyzed Hydrolysis of a Nitrile

108
Q

SN2 formation of Nitriles using Cyanide
and Alkyl Halides

109
Q

Cyanohydrin Formation using
Aldehydes/Ketones and Cyanide

110
Q

Carboxylic Acid Derivative Reactions

111
Q

Self Aldol
Condensation
and Enone
Formation

112
Q

Mixed Aldol
Condensation
and Enone
Formation

113
Q

Self Claisen
Condensation

114
Q

Mixed Claisen
Condensation

115
Q

Dieckmann
Cyclization
(Intramolecular
Claisen
Condensation)

116
Q

Acetoacetic
Ester Synthesis

117
Q

Malonic Ester
Synthesis

118
Q

Alpha
Halogenation
In Basic
Conditions

119
Q

Alpha
Halogenation in
Acidic
Conditions

120
Q

Haloform
Reaction

ORGANIC CHEMISTRY (13 decks)

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