RTR-Atomic structure Flashcards

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1
Q

Give the charge on protons and electrons

A

proton=+1.602 x 10^-19
electron=-1.602 x 10^-19

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2
Q

Give the mass of protons and neutrons

A

proton=1.673x10^-27
nucleus=1.675x10^-27

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3
Q

What force holds protons and neutrons together?

A

Strong nuclear force

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4
Q

What force holds together protons and neutrons?

A

Electrostatic forces

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5
Q

What is the formula to calculate the no.electrons per shell

A

2n^2

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6
Q

Why is a vacuum used in TOF?

A

prevents ions from colliding with air molecules

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7
Q

What is the molecular ion peak? Base peak?

A

Molecular ion peak: peak with the highest m/z ratio
Base peak: tallest peak (most abundant ion)

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8
Q

Define ionization energy

A

Energy required to remove one mole of electrons from one mole of atoms or ions in the gaseous state

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9
Q

Define first and second ionization energies

A

First ionization energies=1+charge
second ionization energies=2+charge
successive ionization energies=1+,2+,3+…

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10
Q

Give the factors which affect ionization energies

A

-nuclear charge
-distance of the outermost electron from the nucleus
-shielding

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11
Q

What is the ionization energy trend down the group

A

decreases (everything increases)

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12
Q

What is the ionization energy across a period

A

increases

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13
Q

How many electrons can each sub-shell hold?

A

S:2
P:6
D:10
F:14

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14
Q

What is the ascending arrangement of subshells?

A

1s, 2s , 2p, 3s, 3p, 4s, 3d, 4p

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15
Q

Electron spin

A

Represented by arrows in the opposite directions

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16
Q

Which two atoms don’t fit the normal electronic configuration pattern?

A

Copper & Chromium

17
Q

Stability rules with electronic configurations

A

An element is more energetically stable if it has a half-filled or fully-filled d-subshell

18
Q

What two groups are there ‘dips’ between?

A

-group 2&3 (less energy to remove electrons from 2p subshell than 2s e.g B+Be)
-group 5&6 electron pairs repel -4e instead of 3)