Rheology Flashcards

1
Q

The study of deformation and flow properties of matter

A

rheology

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2
Q

(main components)
- resistance to flow
- property of liquids

A

viscosity

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3
Q

(main components)
- stickiness or structure
- property of solids

A

elasticity

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4
Q

newtonian systems

A

-shearing stress (F)
-rate of shear (G)
-fluidity
-kinematic viscosity

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5
Q

force per unit area required to bring about a flow

A

Shearing Stress (F)

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6
Q

Directly proportional to shearing stress

A

Rate of Shear (G)

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7
Q

Coefficient of viscosity or VISCOSITY

A

η →Greek letter “eta” [ey-tuh]

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8
Q

unit of viscosity

A

𝑔 / 𝑐𝑚 𝑠𝑒𝑐 𝑜𝑟 Poise (poiz)

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9
Q

centipoise (cp)

A

0.01 poise

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10
Q

Reciprocal of viscosity

A
  • fluidity
  • φ →Greek letter “phi” [fahy]
  • φ = 𝟏 / 𝜼
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11
Q

absolute viscosity divided by density of the liquid at specific temperature,
- 𝝂 = 𝜼 / 𝝆
- ν →Greek letter “nu” [nyoo]

A

kinematic viscosity

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12
Q

unit of measurement for kinematic viscosity

A

stokes (s) or centistokes (cs)

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13
Q

(temperature dependence of viscosity) for liquids: when temperature increases

A

viscosity decreases

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14
Q

why do liquids and their viscosity act accordingly when it comes to their temperature?

A

due to decrease in intramolecular forces of attraction

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15
Q

(temperature dependence of viscosity) for gases: when temperature increases

A

viscosity increases

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16
Q

Examples are simple liquids, either pure chemicals or solutions, water

A

newtonian fluids

17
Q

viscosity of newtonian fluids is ________ on the rate of shear

A

independent

18
Q

Majority of fluid pharmaceutical products do not follow Newton’s law of flow.

A

non-newtonian systems

19
Q

non-newtonian systems are generally exhibited by:

A
  • colloids
  • emulsions
  • suspensions
  • ointments
20
Q

a non-newtonian fluid ________ when under stress or strain

A

changed its behavior

21
Q

(determination of rheologic properties)
- Capillary Viscometer
- Falling Sphere Viscometer

A

newtonian liquids

22
Q

(determination of rheologic properties)
- Rotational Viscometer
(1) Cup and Bob Viscometer
(2) Cone and Plate Viscometer

A

non-newtonian liquids

23
Q

The viscosity of a Newtonian liquid can be determined by measuring the time required for the liquid to pass between two marks as it flows by gravity through a vertical capillary tube.

A

capillary viscometer

24
Q

another name for capillary viscometer

A

ostwald viscometer

25
Q

A glass or steel ball rolls down an almost vertical glass tube containing the test liquid at a known constant temperature. The rate at which a ball of a particular density and diameter falls is an inverse function of the viscosity of the sample.

A

falling sphere viscometer

26
Q

another name for falling sphere viscometer

A

hoeppler viscometer

27
Q

the sample is sheared in the space between the outer wall of a bob and the inner wall of a cup into which the bob fits.

A

cup-and-bob viscometer

28
Q

rotating cup

A

couette type - macmichael viscometer

29
Q

rotating bob

A

searle type - brookfield and stoermer viscometer

30
Q
  • the sample is placed at the center of the plate, which is then raised into position under the cone.
  • A variable-speed motor drives the cone, and the sample is sheared in the narrow gap between the stationary plate and the rotating cone.
A

CONE-AND-PLATE VISCOMETER

31
Q

another name for cone-and-plate viscometer

A

ferranti-shirley viscometer

32
Q

Exhibit both viscous fluidity and elastic solidity when undergoing deformation

A

viscoelasticity