Rheology Flashcards

(32 cards)

1
Q

The study of deformation and flow properties of matter

A

rheology

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2
Q

(main components)
- resistance to flow
- property of liquids

A

viscosity

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3
Q

(main components)
- stickiness or structure
- property of solids

A

elasticity

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4
Q

newtonian systems

A

-shearing stress (F)
-rate of shear (G)
-fluidity
-kinematic viscosity

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5
Q

force per unit area required to bring about a flow

A

Shearing Stress (F)

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6
Q

Directly proportional to shearing stress

A

Rate of Shear (G)

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7
Q

Coefficient of viscosity or VISCOSITY

A

η →Greek letter “eta” [ey-tuh]

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8
Q

unit of viscosity

A

𝑔 / 𝑐𝑚 𝑠𝑒𝑐 𝑜𝑟 Poise (poiz)

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9
Q

centipoise (cp)

A

0.01 poise

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10
Q

Reciprocal of viscosity

A
  • fluidity
  • φ →Greek letter “phi” [fahy]
  • φ = 𝟏 / 𝜼
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11
Q

absolute viscosity divided by density of the liquid at specific temperature,
- 𝝂 = 𝜼 / 𝝆
- ν →Greek letter “nu” [nyoo]

A

kinematic viscosity

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12
Q

unit of measurement for kinematic viscosity

A

stokes (s) or centistokes (cs)

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13
Q

(temperature dependence of viscosity) for liquids: when temperature increases

A

viscosity decreases

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14
Q

why do liquids and their viscosity act accordingly when it comes to their temperature?

A

due to decrease in intramolecular forces of attraction

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15
Q

(temperature dependence of viscosity) for gases: when temperature increases

A

viscosity increases

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16
Q

Examples are simple liquids, either pure chemicals or solutions, water

A

newtonian fluids

17
Q

viscosity of newtonian fluids is ________ on the rate of shear

18
Q

Majority of fluid pharmaceutical products do not follow Newton’s law of flow.

A

non-newtonian systems

19
Q

non-newtonian systems are generally exhibited by:

A
  • colloids
  • emulsions
  • suspensions
  • ointments
20
Q

a non-newtonian fluid ________ when under stress or strain

A

changed its behavior

21
Q

(determination of rheologic properties)
- Capillary Viscometer
- Falling Sphere Viscometer

A

newtonian liquids

22
Q

(determination of rheologic properties)
- Rotational Viscometer
(1) Cup and Bob Viscometer
(2) Cone and Plate Viscometer

A

non-newtonian liquids

23
Q

The viscosity of a Newtonian liquid can be determined by measuring the time required for the liquid to pass between two marks as it flows by gravity through a vertical capillary tube.

A

capillary viscometer

24
Q

another name for capillary viscometer

A

ostwald viscometer

25
A glass or steel ball rolls down an almost vertical glass tube containing the test liquid at a known constant temperature. The rate at which a ball of a particular density and diameter falls is an inverse function of the viscosity of the sample.
falling sphere viscometer
26
another name for falling sphere viscometer
hoeppler viscometer
27
the sample is sheared in the space between the outer wall of a bob and the inner wall of a cup into which the bob fits.
cup-and-bob viscometer
28
rotating cup
couette type - macmichael viscometer
29
rotating bob
searle type - brookfield and stoermer viscometer
30
* the sample is placed at the center of the plate, which is then raised into position under the cone. * A variable-speed motor drives the cone, and the sample is sheared in the narrow gap between the stationary plate and the rotating cone.
CONE-AND-PLATE VISCOMETER
31
another name for cone-and-plate viscometer
ferranti-shirley viscometer
32
Exhibit both viscous fluidity and elastic solidity when undergoing deformation
viscoelasticity