Researching Chemistry Flashcards

1
Q

What are the types of Titrations

A

acid-base
redox
complexometric

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2
Q

How to determine the end point of an acid base titration

A

use indicator with relevant pH

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3
Q

How to make a primary standard

A

calculate mass of primary standard required

weigh standard by difference approximately and then accurately in a standard flask

add small vol of deionised water in a standard flask until it dissolves

Transfer to standard flask

add rinsings

stopper and invert

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4
Q

Characteristics of a primary standard

A

high purity - if not, solution would have lower conc

be stable in air and solution - true conc < calc. value

readily soluble in solvent - conc not as expected

large GFM - large uncertainty in mass weighed out

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5
Q

Examples of a primary standard

A

sodium carbonate

hydrated oxalic acid

potassium iodate

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6
Q

What are accurate results

A

in close agreement with the true/ accepted value

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7
Q

what are precise results

A

in close agreement with each other

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8
Q

What is the DILUTION calculation

A

C1V1 = C2V2

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9
Q

What to do if the dilution question is ION SPECIFIC

A

multiply unknown value by number of ions in the formula

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10
Q

What is the use of a control

A

to VALIDATE an experiment

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11
Q

Steps to a BACK TITRATION

A

Use titration calculation to calculate number of moles of formula IN BOTH CALCULATIONS

ratio it to SUBSTANCE ASKED

Work out actual moles and subtract value from answer 2

Scale to 1 mole

work out mass

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12
Q

What is gravimetric analysis

A

determining the mass of an element in a compound by PRODUCING A PRECIPITATE

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13
Q

What does a desiccator do?

A

prevents sample from absorbing water in air
-DOES NOT REMOVE WATER FROM SAMPLE

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14
Q

How to work out the value of a substance in a hydrated compound

A

work out the mass of water after evaporation

calculate moles of salt and water

calculate ratio

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15
Q

How are organic compounds prepared

A

through REFLUX

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16
Q

Methods of isolation

A

vaccum filtration (solids)
distillation (liquids)
solvent extraction (when the other 2 aren’t possible)

17
Q

How to prevent substance boiling over when heating under reflux

A

anti- bumping granules

18
Q

Techniques used for purification

A

Recrystalisation
Distillation

19
Q

Techniques used to identify a sample:

A

melting point
boiling point
TLC

20
Q

What is recrystallisation used for

A

to purify solids based on solubility

21
Q

Reasons for Reduced % yield

A

loss of product / mass
side reaction
incompletion of experiment (equilibrium)

22
Q

What if a substance has loads of impurities

A

Low MP

23
Q

What if a substance has little impurities

A

High MP
Small temp change

24
Q

Rules to remember for solvent extraction

A

more soluble in new solvent than current solvent

solvents must be IMMISCIBLE (like water and oil)

25
Q

what is the purpose of a dessicator

A

prevent reabsorption of water

26
Q

3 funnels for vacuum filtration

A

Buchner
Hirsch
Centred glass