Atomic Orbitals Flashcards

1
Q

What is the acronym to remember the electromagnetic spectrum

A

red
martians
invade
venus
using
X-ray
guns

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2
Q

What increases across the electromagnetic spectrum

A

energy and frequency

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3
Q

What decreases along the EM spectrum

A

wavelength

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4
Q

Electromagnetic spectrum question equation

A

C=f(lamda)

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5
Q

Explain the lines on emission spectra

A

Electron absorbs energy from heat or flame and is promoted to a higher energy level (excited state)
When the electron falls, it releases energy in the form of a wave

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6
Q

How to identify elements

A

Use their own spectra
(each element has their own)

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7
Q

How to calculate energy associated with wavelength

A

E=LHF or E=LHC/1000(lamda)

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8
Q

What is the principal quantum number

A

main energy level (n)
- can have value from 1 onwards

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9
Q

What is the angular momentum quantum number

A

the number of the subshell (l)
-value from 0 to n-1

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10
Q

What is the magnetic quantum number

A

the number of orbitals in each sub-shell (m)
- can take values from -l to +l

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11
Q

What is the term used to describe orbitals with the same energy

A

degenerate

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12
Q

What is the spin quantum number

A

the direction the electron is spinning in (ms)

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13
Q

What is the Aufbau principal?

A

energy levels filled up by increeasing energy

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14
Q

What is the pauli exclusion principle

A

electrons must have opposite spins

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15
Q

What is Hunds rule

A

each orbital must be filled before electrons start pairing up

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16
Q

What is ionisation energy

A

the energy required to remove 1 mol of e from 1 mol of atoms in the gaseous state

17
Q

What is the second ionisation energy

A

the energy required to remove 1 mole of e from 1 mol of the positive ion

18
Q

Why is it easy to remove an electron from aluminium than it is magnesium?

A

magnesium has a full sub shell which is therefore more stable than 3p1 in aluminium

19
Q

Why is the ionisation energy for nitrogen higher than oxygen?

A

all orbitals are half filled in nitrogen, making it more stable