Required Practical 4 Flashcards
Test 1
G2 metal cations (with NaOH)
BaCl2
CaBr2
MgCl2
SrCl2
Add sodium hydroxide solution, record result then add sodium hydroxide solution in excess and record the result.
Test 1
BaBr2 + sodium hydroxide solution
BaBr2 (aq) + 2NaOH (aq) —> Ba(OH)2 (aq) +2NaBr (aq)
NaOH - colourless solution
Excess NaOH - colourless solution
Test 1
CaCl2 + sodium hydroxide solution
CaCl2 (aq) + 2NaOH (aq) —> Ca(OH)2 (s) +2NaCl (aq)
Ca(OH)2 - slightly soluble
NaOH -slight - slight white precipitate
Excess NaOH - slight white precipitate
Test 1
MgCl2 + sodium hydroxide solution
MgCl2 (aq) + 2NaOH (aq) —> Mg(OH)2 (s) +2NaCl (aq)
NaOH - white precipitate
Excess NaOH - white precipitate
Test 1
SrCl2 + sodium hydroxide solution
SrCl2 (aq) + 2NaOH (aq) —> Sr(OH)2 (aq) +2NaCl (aq)
NaOH - slight white precipitate
Excess NaOH - colourless solution
Test 2
G2 metal cations (with H2SO4)
BaCl2
CaBr2
MgCl2
SrCl2
Add 1 drop of sulphuric acid, record result then add 5 drops sulphuric acid and record the result.
Test 2
BaCl2 + sulphuric acid
BaCl2 (aq) + H2SO4 (aq) —> BaSO4(s) + 2HCl(aq)
1 drop H2SO4 - white precipitate
5 Drops H2SO4 - white precipitate
Test 2
CaBr2 + sulphuric acid
CaBr2 (aq) + H2SO4 (aq) —> CaSO4(aq) + 2HBr(aq)
1 drop H2SO4 - slight white precipitate
5 Drops H2SO4 - colourless solution
Test 2
MgCl2 + sulphuric acid
MgCl2 (aq) + H2SO4 (aq) —> MgSO4(aq) + 2HCl(aq)
1 drop H2SO4 - colourless solution
5 Drops H2SO4 - colourless solution
Test 2
SrCl2 + sulphuric acid
SrCl2 (aq) + H2SO4 (aq) —> SrSO4(s) + 2HCl(aq)
SrSO4 - slightly soluble
1 drop H2SO4 - slight white precipitate
5 Drops H2SO4 - slight white precipitate
Test 3
Ammonium ions (from NH4Cl)
NH4Cl - ammonium chloride
Add sodium hydroxide solution, observe.
Test 3
ammonium chloride + sodium hydroxide solution
NH4Cl(aq) + NaOH(aq) —> NH3(g) + H2O(l) + NaCl(aq)
Litmus paper turns red to blue
(Effervescence from NH3 gas)
Test 4
Anions in aqueous solution (ammonia solution)
Ammonia solution + damp red litmus paper will turn blue.
The ammonia solution reacts with the water on the litmus paper to produce ammonia hydroxide which is alkaline.
Test 4
Water + ammonia
H2O(l) + NH3(aq) —> NH4+ (g) + OH- (aq-)
Test 5
Carbonate ions in aqueous solution
Add sodium Hydroxide solutions and dilute hydrochloric acid.
Positive result - white precipitate
Test 5
Calcium carbonate + Sodium hydroxide solution
CaCO3(aq) + NaOH(aq) + 2HCl(aq) —> NaHCO3(s) + CaCl2(aq) + H2O(l)
Test 6
Sulphate ions in aqueous solution
Add dilute hydrochloric acid (remove impurities) and barium chloride.
Positive result - white precipitate
Test 6
Magnesium sulphate + barium chloride + dilute hydrochloric acid
MgSO4(aq) + BaCl2(aq) —> BaSO4(s) + MgCl2 (aq)
Test 7a
Halide ions in aqueous solution (with nitric acid and silver nitrate)
Add nitric acid, record observations then add 1 drop of silver nitrate solution and record the observations.
Test 7a
Halide ions in aqueous solution (with nitric acid observations)
Nitric acid - all remain colourless solutions
KCl = Cl-(aq) + Ag+(aq) —> AgCl(s)
Test 7a
KCL in aqueous solution (with nitric acid and silver nitrate observations and equations)
KCl = Cl-(aq) + Ag+(aq) —> AgCl(s)
White precipitate
Test 7a
KBr in aqueous solution (with nitric acid and silver nitrate observations and equations)
KBR = Br-(aq) + Ag+(aq) —> AgBr(s)
Cream precipitate
Test 7a
KI in aqueous solution (with nitric acid and silver nitrate observations and equations)
KI = I-(aq) + Ag+(aq) —> AgI(s)
Yellow precipitate
Test 7b
Halide ions in aqueous solution (ammonia)
Add dilute ammonia, record observations
Add concentrated ammonia, record observations.
Test 7b
AgCl in aqueous solution (+ dilute and concentrated ammonia)
Dilute - precipitate dissolves, colourless solution
Conc - precipitate dissolves, colourless solution
Test 7b
AgBr in aqueous solution (+ dilute and concentrated ammonia)
Dilute - slight cream precipitate
Conc - precipitate dissolves, colourless solution
Test 7b
AgI in aqueous solution (+ dilute and concentrated ammonia)
Dilute - yellow precipitate
Conc - yellow precipitate
Test 8
Halide ions in solid salts
Add concentrated sulphuric acid + test with blue litmus paper turns red
(can be plain or dipped in acidified K2Cr2O7 or lead solution)
Test 8
KCl in solid salts
Add Concentrated sulphuric acid + blue litmus paper.
Observation - green gas + Blue litmus paper turned red.
2KCl(aq) + 2H2SO4(aq) —> SO2(g) + Cl2(g) + K2SO4(aq) + 2H2O(aq)
Test 8
KBr in solid salts
Concentrated sulphuric acid + blue litmus paper dipped in acidified potassium dichromate solution.
Observation - orange gas + Blue litmus paper turns red
2KBr(aq) + H2SO4(aq) —> SO2(g) + Br2(g) + K2SO4(aq) + 2H2O(aq)
Test 8
KI in solid salts
Concentrated sulphuric acid + blue litmus paper dipped in lead nitrate solution.
Observation - purple gas and black solid + Blue litmus paper turns red
2KI(aq) + H2SO4(aq) —> SO2(g) + I2(s) + K2SO4(aq) + 2H2O(l)