Remember Stuff Flashcards
In the equation pV=nRT what are the units
p - Pa
V- m3
T - K +273 but not if using a difference in temp
cm3 to dm3
divide by 1000
dm3 to m3
divide by 1000
What is the name and bonding angles for a molecule with
2 regions of electron density
- Linear
- 120
What is the name and bonding angles for a molecule with
3 regions of electron density
- Trigonal Planar
- 109.5
What is the name and bonding angles for a molecule with
4 regions of electron density
- Tetrahedral
- 109.5
What is the name and bonding angles for a molecule with
5 regions of electron density
- Trigonal Bipyramidal
- 90
- 120
What is the name and bonding angles for a molecule with
6 regions of electron density
- Octahedral
- 90
By how much is the bonding angle reduced for every lone pair
2.5
What is the Carbonate Test
- Add dilute nitric Acid
- Positive Result - Bubbles of gas
What is the Sulphate Test
- Add Barium Nitrate
- Positive Result - White Precipitate
What is the halide Test
- Add silver nitrate solution to a test tube
- Positive result:
* Cl- White Precipitate - soluble in d. NH3
* Br- Cream Precipitate - soluble in c. NH3
* I- Yellow Precipitate - insoluble in c. NH3
What is the order of the Anion tests
- Carbonate
- Sulphates
- Halide
What is the Ammonium Test
- Add aq NaOH
- Positive result - Gas released turns moist litmus paper blue
How do you go from an Alkene to an alcohol
- H20 Steam
- H3PO4 Catalyst
How do you go from an alkane to a haloalkane and what is the name of the mechanism
- Halogen
- UV
- Radical Substitution
How do you go from an Alkene to an Alkane and what is the name of the reaction
- H2
- Ni Catalyst
- Hydrogenation
How do you go from an alkene to a haloalkane and what is the name of the mechanism
- Hydrogen Halide / Halogen
- Electrophillic Addition
How do you go from an alcohol to an alkene
- Add c. H2SO4 or c. H3PO4
- Reflux
How do you go from a halolkane to an alcohol and what is the name of the mechanism
- NaOH (aq)
- Reflux
- Nucleophillic Substitution
How do you go from an alcohol to a haloalkane
- Sodium Halide
- H2SO4
- Reflux
How do you go from a Primary alcohol to a Carboxyllic Acid
- Acidified Dichromate Ions
- Reflux
How do you go from a Secondary Alcohol to a ketone
- Acidified Dichromate Ions
- Reflux
How do you go from a Primary Alcohol to an aldehyde
- Acidified Dichromate Ions
- Distill
How do you go from an aldehyde to a Carboxylic Acid
Acidified Dichromate Ions
Show the catalysis of the breakdown of ozone by radical X
X· + O3 → XO· + O2
XO· + O → X· + O2
Overall : O3 + O → 2O2
Write the equations of the radical substitution of C5H12 with Br2
- Initiation
* Br–Br –> Br· + Br· - Propagation
* C5H12 + Br· –> ·C5H11 + HBr·
* ·C5H11 + Br2 –> C5H11Br + Br· - Termination
* Br· + Br· –> Br2
* ·C5H11 + Br· –> C5H11Br
* ·C5H11 + ·C5H11 –> C10H22
Overall
C5H12 + Br2 –> C5H11Br + HBr