Chapter 13 - Alkenes Flashcards

1
Q

What is a polymer

A

A polymer consists of many repeat units (monomers) joined together to make a long chain

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2
Q

How do alkenes form long saturated polymer chains

A

They undergo addition polymerisation

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3
Q

What are some uses for Polythene

A

Shopping bags

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4
Q

What are some uses for Polychloroethene and what is it more commonly known as

A

PVC
* Pipes
* Floor tiles

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5
Q

What are some uses for Polypropene

A
  • Crates
  • Ropes
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6
Q

What are some uses for

A
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7
Q

What are some uses for Polytetrafluoroethene PTFE

A

Non-stick pans

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8
Q

What are problems with recycling polymers

A

Costly to sort by hand
Mixed polymers renders the product unusable
PVC recycling - Releases toxic hydrogen chloride and dioxins when burnt

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9
Q

What are positive aspects to recycling polymers

A
  • Conserves finite fossil fuels and decreases amount of waste going into landfill
  • Waste polymers can be incinerated to produce heat, generating steam to power turbines producing electricity
  • Reclaiming monomers from waste polymers which can be used as raw materials for the production of new polymers
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10
Q

What are biodegradable polymers

A

Polymers that are broken down by bacteria into water, carbon dioxide, and biological compounds

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11
Q

What are photodegradable polymers

A

Polymers containing bonds weakened by absorbing light

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12
Q

What is Markownikoff’s rule

A

The stability of the carbocation intermediate increases the more alkyl groups there are attached to the positively charged carbon atom

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13
Q

Why are alkenes much more reactive than alkanes

A
  • The π-electrons are more exposed than the σ-electrons as they
    are on the outside of the double bond
  • The π-bond readily breaks and alkenes undergo addition
    reactions relatively easily
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14
Q

What conditions are required for hydrogenation of alkenes

A

Nickel Catalyst

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15
Q

What conditions are required for the halogenation of alkenes

A

React with Chlorine and Bromine at room temperature

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16
Q

What conditions are required for alkenes to react with hydrogen halides

A

Room Temperature

17
Q

What conditions are required for the hydration of Alkenes

A

Steam
Phosphoric acid Catalyst

18
Q

How do you test for the presence of a C=C double bond and what is the change

A
  • Add bromine water
  • The orange colour goes colourless
19
Q

What is Cis-Trans isomerism

A
  • Must have a C=C double bond
  • Two different groups must be attached to each carbon of the double bond
  • One of the attached groups on each carbon must be the same