Redox Titration Flashcards

1
Q

It is a number assigned to an element in a compound which enables us to describe oxidation-reduction reactions and balancing redox chemical reactions.

A

Oxidation state

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2
Q

most common source of error; caused by resistance to the flow of charge at a boundary

A

junction potential

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3
Q

It consumes electrical energy from an external source, using it to cause a nonspontaneous redox reaction to occur ( ΔG>0 ).

A

Electrolytic cell

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4
Q

These are shown by single vertical lines

A

Phase boundaries

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5
Q

The _______________ is the substance that loses electrons and is oxidized in the process

A

reductant

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6
Q

The reaction of gaseous hydrogen chloride and iron oxide is a __________________________

A

double replacement reaction

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7
Q

energy released by spontaneous redox reaction is converted to electrical energy

A

galvanic cell

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8
Q

It relates the potential, E, to the standard electrode potential, E⁰ by the following equation

A

Nernst equation

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9
Q

Oxidation state enables us to describe __________________ and _____________________.

A

oxidation-reduction reactions, balancing redox chemical reactions

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10
Q

The oxidation number of a monatomic (composed of one atom) ion is the same as the ________ of the ion

A

charge

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11
Q

It is considered to be any element in an uncombined state, whether monatomic or polyatomic.

A

free element

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12
Q

There is no net change in the number of electrons in a

A

redox reaction

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13
Q

In molecular compounds, the names are given which refer to the ________________ present in the compound.

A

number of molecules

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14
Q

An ________________________ is any chemical reaction in which the oxidation number of a molecule, atom, or ion changes by gaining or losing an electron.

A

oxidation-reduction reaction

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15
Q

In ionic compounds, the names are given which refer to the ___________________.

A

oxidation (ionic) state

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16
Q

It uses the energy released during a spontaneous redox reaction (ΔG<0) to generate electricity.

A

Galvanic (voltaic) cell

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17
Q

electrical energy is used to drive nonspontaneous redox reaction

A

electrolytic cell

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18
Q

ΔG < 0

A

reaction can spontaneously proceed to the right

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19
Q

reduced, accepts electrons, oxidation number decreases

A

oxidizing agent

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20
Q

In ionic and covalent molecular compounds, usually the ____________________ element is given first.

A

less electronegative

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21
Q

OIL RIG

A

“oxidation is loss” and “reduction is gain,“

22
Q

LEO says GER

A

“loss of e- = oxidation” and “gain of e- = reduced.”

23
Q

When the circuit is closed, electrons flow from the _________ to the ____________

A

anode, cathode

24
Q

____________________ have some practical significance in everyday life, including the reaction of hydrogen peroxide, H2O2 poured over a cut.

A

Disproportionation reactions

25
In a neutral molecule, the sum of the oxidation numbers of all atoms is _______
zero
26
A redox reaction can be described as ____________________, one representing the oxidation process and one the reduction process.
two half-reactions
27
In ______________________ the names are given which refer to the oxidation (ionic) state.
ionic compounds
28
ΔG > 0
reaction can spontaneously proceed to the left
29
It is an apparatus that is used to generate electricity from a spontaneous redox reaction or, conversely, that uses electricity to drive a nonspontaneous redox reaction
Electrochemical cell
30
it is where reduction half-reaction occurs
cathode
31
it is where oxidation half-reaction occurs
anode
32
Oxidation-Reduction Reaction comprised of two parts
1. reduced half 2. oxidized half
33
There is no ___________ in the number of electrons in a redox reaction.
net change
34
The ___________ of the cell, measured in volts, is the difference in electrical potential between the two half-reactions and is related to the energy needed to move a charged particle in an electric field.
potential
35
“Red Cat An Ox”
Reduction in cathode; Oxidation in anode
36
the _____________ is the species that gains electrons and is reduced in the process
oxidant
37
The oxidation number of an atom in a neutral free element is __________.
zero
38
It is the movement of an electron from one atom to another.
Electron transfer
39
In ___________________, the names are given which refer to the number of molecules present in the compound.
molecular compounds
40
Both types contain _________________, which are solid metals connected to an external circuit that provides an electrical connection between the two parts of the system.
two electrodes
41
Phase boundaries are shown by?
single vertical lines
42
charge an atom would possess if the bonding were ionic
oxidation state
43
This does not need to begin with neutral molecules and can involve more than two species with differing oxidation states (but rarely).
Disproportionation reactions
44
The identity of the electrodes and the chemical contents of the compartments are indicated by their chemical formulas, with the anode written on the far ____ and the cathode on the far _____.
left, right
45
ΔG = 0
the reaction is at equilibrium
46
It is a useful tool for keeping track of electron transfers especially for transition metals.
Oxidation state
47
single substance can be both oxidized and reduced in some redox reactions. These are known as ________________________________
disproportionation reactions
48
The associated ______________________ is determined by the potential difference between the valence electrons in atoms of different elements.
potential energy
49
oxidized, donates electrons, oxidation number increases
reducing agent
50
charge that results when the electrons in a covalent bond are assigned to the more electronegative atom
oxidation state