redox Flashcards
oxidation - define
loss of electrons
gain of O2
loss of H2
increase in oxi number
reduction - define
gain of electrons
loss of O2
gain of H2
decrease in oxi number
oxidising agent
readily accept electrons, and substance that is reduced
activity series
higher up = stronger reducing agent/oxident and more reactive
lower = weaker reducing agent/reductant
in voltaic cell: anode = and cathode =
anode = -ve electrode and its oxidising
cathode = + electrode and its reducing
electrolytic cell: anode = and cathode =
anode = +ve electrode and its oxidising
cathode = -ve electrode and its reducing
rules for oxi numbers
- ionic compound - each element takes its charge
- covalent compound - more electronegative takes negative change as if ionic
- sum of all oxi numbers in compound = 0
- sum of all oxi numbers in ion = charge on ion
elements have an oxi number of 0 - Oxygen has oxi number of -2 except as H2O2 when its -1
- hydrogen has oxi number of +1
reducing agent
readily donate electrons, and substance that is oxidised
salt bridge
+ve cations move towards the cathode and -ve anions move towards the anode through the salt bridge to prevent build-up of ionic charge in half cell - completes the circuit
oxidation always happens at the
anode