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Z - Chem 2220 (S&T) Organic Chemistry II > Reagents Chapter 17 > Flashcards

Reagents Chapter 17 Flashcards

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1
Q

KMnO4 + Aromatic Alkane

A

Carboxylic acid. Will replace the most acid H, or the group on the benzene ring.

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2
Q

KMnO4 + Aldehyde

A

Carboxylic acid anion. The KMnO4 will replace the H with O-. A later addition of an acid would protonate.

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3
Q

KMnO4 + Alcohol

A

Carboxylic acid. =O replaces the hydrogens of the Alcohol carbon.

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4
Q

Ag2O + Aldehyde

A

Carboxylic acid anion.

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5
Q

Ag(NH3)2+ + Aldehyde

A

Carboxylic acid anion.

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6
Q

CrO3 or H2CrO4 + Aldehyde

A

Carboxylic acid.

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7
Q

CrO3 or H2CrO4 + Alcohol

A

Carboxylic acid.

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8
Q

K2Cr2O7 + Alcohol

A

Carboxylic acid.

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9
Q

Alcohol + Carboxylic Acid

A

Ester. The H of the Alcohol combines with the OH of the Carboxylic acid and leaves as a H2O

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10
Q

Alcohol + Acid Chloride

A

Ester. The H of the Alcohol combines with the Cl of the Acid Chloride and leaves

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11
Q

Alcohol + Anhydride

A

Ester and/or Carboxylic Acid. Carboxylic on side that keeps its Oxygen, add OR to side that doesn’t.

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12
Q

Alcohol + Ester

A

Different Ester. Different Alcohol (?)

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13
Q

Alcohol + Amide

A

No reaction.

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14
Q

Amine (R2NH) + Carboxylic Acid

A

Amide.

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15
Q

Amine (R2NH) + Acid Chloride

A

Amide.

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16
Q

Amine (R2NH) + Anhydride

A

Amide + Carboxylic Anion. Splits at the Oxygen

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17
Q

Amine (R2NH) + Ester

A

Amide

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18
Q

RMgX or RLi + CO2

A

Carboxylic Acid

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19
Q

RMgX or RLi + Carboxylic Acid

A

Carboxylic Acid Anion and RH

NO REACTION

20
Q

RMgX or RLi + Acid Chloride

A

3* Alcohol

21
Q

RMgX or RLi + Anhydride

A

3* Alcohol

22
Q

RMgX or RLi + Ester

A

3* Alcohol. The OR of the Ester leaves and could be protonated

23
Q

RMgX or RLi + Amide

A

RH and Amide Anion. (R will steal the H on the nitrogen)

24
Q

LiAlH4 + Carboxylic Acid

A

1* Alcohol

25
Q

LiAlH4 + Acid Chloride

A

1* Alcohol

26
Q

LiAlH4 + Anhydride

A

1* Alcohol

27
Q

LiAlH4 + Ester

A

1* Alcohol

28
Q

LiAlH4 + Amide

A

Amine (=O gets replaced with -H, -H)

29
Q

LiAl(OBu)3H + Carboxylic Acid

A

NO REACTION

30
Q

LiAl(OBu)3H + Acid Chloride

A

Aldehyde

31
Q

LiAl(OBu)3H + Ester

A

Aldehyde

32
Q

LiAl(OBu)3H + Amide

A

Aldehyde

33
Q

H2O + Carboxylic Acid

A

Carboxylic Acid Anion

34
Q

H2O + Acid Chloride

A

Carboxylic Acid

35
Q

H2O + Anhydride

A

Carboxylic Acid (2)

36
Q

H2O + Ester

A

Carboxylic Acid

37
Q

H2O + Amide

A

Carboxylic Acid

38
Q

H3O+ + Amide

A

Carboxylic Acid

39
Q

OH- + Carboxylic Acid

A

Carboxylic Acid Anion

40
Q

OH- + Acid Chloride

A

Carboxylic Acid Anion

41
Q

OH- + Anhydride

A

Carboxylic Acid Anion

42
Q

OH- + Ester

A

Carboxylic Acid Anion

43
Q

OH- + Amide

A

Carboxylic Acid Anion

44
Q

Carboxylic Acid or its Anion + Acid Chloride

A

Anhydride

45
Q

Benzene and AlCl3 + Acid Chloride

A

Ketone

46
Q

Acid Chloride + Base (like pyridine) + Carboxylic Acid

A

Anhydride

47
Q

SOCl2 or (COCl)2 or PCl5 or PCl3 + Carboxylic Acid

A

Acid Chloride

Z - Chem 2220 (S&T) Organic Chemistry II (12 decks)

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