Reagents Flashcards

0
Q

Things you can turn an acid chloride into

A

Ketone, aldehyde, amide, ester, anhydride

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1
Q

SOCl2

A

Turns a carboxylic acid into an acid chloride

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2
Q

Turn acid chloride into amide

A

Add amine

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3
Q

Acid chloride to ester

A

Add alcohol or phenol

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4
Q

Acid chloride to anhydride

A

Add carboxylate

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5
Q

Acid chloride to ketone

A

Add cuprate in THF, and H2O

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6
Q

Acid chloride to aldehyde

A

Add H2 over a Pd/C and quinoline

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7
Q

What does DIBAL do?

A

Reduces things down to aldehydes

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8
Q

Lactone in DIBAL and H3O+

A

Turns the carbonyl into an alcohol for a major product, and a primary alcohol on one end and aldehyde on the other for a minor product

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9
Q

Aldehyde + Grignard and H3O+

A

Adds Grignard to the aldehyde hydrogen, and changes carbonyl to an alcohol

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10
Q

MnO2 in DCM (include limitations)

A

Turns the alcohol into a ketone, but normally not for primary alcohols unless they are stabilized. (Conjugated alkene)

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11
Q

What is one way to form an anhydride?

A

Add an acid chloride in pyridine to a carboxylic acid.

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