reactivity trends Flashcards

1
Q

explain trend in boiling point group 7

A
  • size of atom increases
  • number of electrons increases
  • more London forces of attraction
  • stronger intermolecular forces
  • more energy required to break these
  • increased down the group
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2
Q

trend in reactivity down group 7

A
  • reactivity decreases
  • atomic radius decreases
  • shielding decreases
  • less nuclear attraction
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3
Q

group 2 reactivity

A
  • more reactive as you go down
  • atomic radius increases
  • more shielding
  • nuclear attraction decreases
  • less energy needed to remove electrn
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4
Q

Reaction of group 2 element with water

A

Hydroxide and hydrogen gas

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5
Q

Group 2 element react with acid

A

Salt and hydrogen

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6
Q

Group 2 oxide react with water

A

Make metal hydroxide

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7
Q

Most reactive metal group 2

A

Barium

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8
Q

What happens to first ionisation energy as you go down group 2

A

Decreases
more shielding
larger atomic radius
less nuclear attraction

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9
Q

How would calcium react with water instead of strontium

A

Less effervescence
Dissolves slower
Less soluble
Lower ph/less alkaline

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10
Q

Equation for fourty ionisation energy of strontium

A

Sr3+->Sr4+ +e-

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11
Q

bond enthalpy group 7

A

decreases as you go down so hydrolyses faster

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12
Q

testing reactivity

A

add silver nitrate and ethanol to chloroalkane, bromoalkane and iodoalkane
yellow precipitate forms first - iodide
cream second - bromide
white last - chloride

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13
Q

Why is it unrective

A

Non polar

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14
Q

Radical

A

Species with unpaired electron

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15
Q

Type of bond breaking in radical substitution

A

Homolytic

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16
Q

Why carry out trial titration

A

To estimate titre

17
Q

What happens if you wash Pipette with water instead of the acid given

A

Acid is less concentrated

18
Q

Why is using low temp beneficial to environment

A

Less fossil fuel used
Reduces CO2 emission

19
Q

Advantage and disadvantage of using msss balance instead of gas collection

A

Advantage : no loss of gas
Disadvantage : small loss in mass

20
Q

How to obtain pure dry sample from mixture

A

Separating funnel ti separate organic layer from aqueous
Drying agent (anhydrous calcium chloride)
Organic layer is top layer
Distillation to purify