enthalpy and entropy Flashcards

1
Q

enthalpy change of formation

A

standard enthalpy change of a compound when
1 mole of the compound is formed from its elements under standard conditions

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2
Q

enthalpy of atomisation

A

the enthalpy change when 1 mole of gaseous atoms is formed
from the element in its standard state

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3
Q

Enthalpy of sublimation

A

(same as enthalpy of atomisation)
The enthalpy change for a solid metal turning
to gaseous atoms

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4
Q

First Ionisation enthalpy

A

the enthalpy change
required to remove 1 mole of electrons from 1 mole
of gaseous atoms to form 1 mole of gaseous ions (with a 1+ charge)

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5
Q

First Electron affinity

A

the enthalpy change that
occurs when 1 mole of gaseous atoms gain 1 mole of
electrons to form 1 mole of gaseous ions with a –1 charge. usually exothermic

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6
Q

Lattice Enthalpy

A

the standard enthalpy change
when 1 mole of an ionic crystal lattice is formed from
its constituent ions in gaseous form.

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7
Q

Enthalpy of Hydration

A

Enthalpy change when one mole of gaseous ions
become aqueous ions . ALWAYS EXOTHERMIC

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8
Q

Enthalpy of solution

A

the standard enthalpy
change when one mole of an ionic solid dissolves in
water.

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9
Q

why is the 1st electron affinity exothermic

A

the ion is more
stable than the atom and there is an attraction
between the nucleus and the electron

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10
Q

why is the 2nd electron affinity endothermic

A

it takes energy to overcome
the repulsive force between the negative ion and
the electron

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