enthalpy and entropy Flashcards
enthalpy change of formation
standard enthalpy change of a compound when
1 mole of the compound is formed from its elements under standard conditions
enthalpy of atomisation
the enthalpy change when 1 mole of gaseous atoms is formed
from the element in its standard state
Enthalpy of sublimation
(same as enthalpy of atomisation)
The enthalpy change for a solid metal turning
to gaseous atoms
First Ionisation enthalpy
the enthalpy change
required to remove 1 mole of electrons from 1 mole
of gaseous atoms to form 1 mole of gaseous ions (with a 1+ charge)
First Electron affinity
the enthalpy change that
occurs when 1 mole of gaseous atoms gain 1 mole of
electrons to form 1 mole of gaseous ions with a –1 charge. usually exothermic
Lattice Enthalpy
the standard enthalpy change
when 1 mole of an ionic crystal lattice is formed from
its constituent ions in gaseous form.
Enthalpy of Hydration
Enthalpy change when one mole of gaseous ions
become aqueous ions . ALWAYS EXOTHERMIC
Enthalpy of solution
the standard enthalpy
change when one mole of an ionic solid dissolves in
water.
why is the 1st electron affinity exothermic
the ion is more
stable than the atom and there is an attraction
between the nucleus and the electron
why is the 2nd electron affinity endothermic
it takes energy to overcome
the repulsive force between the negative ion and
the electron