Reactions Equations Flashcards

1
Q

What is the combustion reaction for alkanes?

A

Alkane + O2 -> CO2 + H2O

Excess Oxygen

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2
Q

What is the process for free radical substitution of alkanes?

A

Alkane + Halogen in UV Light -> Halogenoalkane

Free Radical Substitution

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3
Q

What is the nucleophilic substitution reaction for halogenoalkanes with OH-?

A

Halogenoalkane + NaOH -> Alcohol + Halide Ion

Heat under reflux, Aqueous

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4
Q

What is the nucleophilic substitution reaction for halogenoalkanes with CN-?

A

Halogenoalkane + NaCN/KCN -> Nitrile + Halide Ion

Heat under reflux, Ethanolic

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5
Q

What is the nucleophilic substitution reaction for halogenoalkanes with NH3?

A

Halogenoalkane + NH3 -> Amine + Ammonium Halide Salt

Heat, Ethanolic

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6
Q

What is the substitution and elimination reaction for halogenoalkanes with OH-?

A

Halogenoalkane + KOH -> Alcohol + Alkene

Heat under reflux, Ethanolic or Aqueous

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7
Q

What is the electrophilic addition reaction for alkenes with HBr?

A

Alkene + HBr -> Bromoalkane

HBr Gas or Concentrated HBr

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8
Q

What is the electrophilic addition reaction for alkenes with Br2?

A

Alkene + Br2 -> Dibromoalkane

Bromine Liquid or Bromine Water

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9
Q

What is the hydration reaction for alkenes?

A

Alkene + H2O(g) -> Alcohol

Heat, Phosphoric Acid Catalyst

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10
Q

What is the hydrogenation reaction for alkenes?

A

Alkene + H2 -> Alkane

150°C, Nickel Catalyst

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11
Q

What is the oxidation reaction for alkenes to form diols?

A

Alkene + KMnO4 (dilute) -> Diol

Cold, Acidic

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12
Q

What is the oxidation reaction for alkenes that breaks the C=C bond?

A

Alkene + KMnO4 (conc.) -> Two Carbonyl Molecules

Hot, Acidic

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13
Q

What is the addition polymerisation reaction for alkenes?

A

Alkene -> Poly(alkene)

Addition Polymerisation

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14
Q

What is the oxidation reaction for alcohols?

A

Alcohol + Cr2O7^2-/H+ -> Aldehyde/Ketone/Carboxylic Acid

Heat, H2SO4

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15
Q

What is the halogenation reaction for alcohols with PCl5?

A

Alcohol + PCl5 -> Chloroalkane + HCl

No Water Present

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16
Q

What is the halogenation reaction for alcohols with KBr?

A

Alcohol + KBr + H2SO4 -> Bromoalkane

Warm, Distillation

17
Q

What is the elimination reaction for alcohols?

A

Alcohol -> Alkene

Heat, H2SO4 or H3PO4

18
Q

What is the reaction of alcohols with sodium?

A

Alcohol + Na -> Alkoxide + Na+

-

19
Q

What is the reduction reaction for aldehydes?

A

Aldehyde + NaBH4 -> Primary Alcohol

-

20
Q

What is the reduction reaction for ketones?

A

Ketone + NaBH4 -> Secondary Alcohol

-

21
Q

What is the formation reaction for hydroxynitriles?

A

Carbonyl + KCN (acidic) -> Hydroxynitrile

-

22
Q

What is the reduction reaction for carboxylic acids?

A

Carboxylic Acid + LiAlH4 -> Primary Alcohol

Dry Ether

23
Q

What is the esterification reaction for esters?

A

Carboxylic Acid + Alcohol -> Ester

Heat, H2SO4 Catalyst

24
Q

What is the hydrolysis reaction for esters?

A

Ester -> Carboxylic Acid + Alcohol

Warm, Aqueous (Acid or Alkali)

25
What is the acid hydrolysis reaction for nitriles?
Nitrile + HCl -> Carboxylic Acid + NH4Cl ## Footnote Heat under Reflux