reaction scheme Flashcards
alkene to alkyne
elimination
NaNH2
alkene to dihaloalkane
addition
X2 (aq) = two halides
alkene to diol
oxidation
MnO4/H+ (reflux) only sometimes acidified = purple to colourless
not acidified = purple to brown solid
can be used as a test for alkene as alkane don’t break bonds
alkene to alcohol
addition
H2O/H+, heat
alkene to haloalkane
addition
Hx
alkene to alkane
addition
H2/Pt catalyst, heat
alkane to haloalkane
substitution
X2 (aq), slow, UV light
product = monohaloalkane + hydrogen halide
haloalkane to alkene
elimination
KOH (alc)
alcohol to alkene
elimination
concentrated H2SO4, heat
alcohol to haloalkane
Substitution HCl
PCl3, PCl5, SOCl2, heat
products = haloalkane + water as both the OH and H is removed and replaced with HCl
haloalkane to alcohol
substitution
KOH (aq) (reflux)
products = alcohol and potassium + halide
haloalkane to amine
substitution
NH3 (alc), warm
product = amine + hydrogen halide
amine to ammonium salt
neutralisation
acid (H+)
alcohol to carboxylic acid
oxidation
MnO4-/H+ or Cr2O72-/H+ reflux
test for primary alcohol with Cr2O72- goes from orange to green as ions are reduced and dichromate doesn’t react with any other functional group
MnO4- goes from purple to colourless
carboxylic acid to carboxylate salt
neutralisation
base (OH-)