reaction scheme Flashcards

1
Q

alkene to alkyne

A

elimination
NaNH2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

alkene to dihaloalkane

A

addition
X2 (aq) = two halides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

alkene to diol

A

oxidation
MnO4/H+ (reflux) only sometimes acidified = purple to colourless
not acidified = purple to brown solid
can be used as a test for alkene as alkane don’t break bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

alkene to alcohol

A

addition
H2O/H+, heat

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

alkene to haloalkane

A

addition
Hx

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

alkene to alkane

A

addition
H2/Pt catalyst, heat

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

alkane to haloalkane

A

substitution
X2 (aq), slow, UV light
product = monohaloalkane + hydrogen halide

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

haloalkane to alkene

A

elimination
KOH (alc)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

alcohol to alkene

A

elimination
concentrated H2SO4, heat

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

alcohol to haloalkane

A

Substitution HCl
PCl3, PCl5, SOCl2, heat
products = haloalkane + water as both the OH and H is removed and replaced with HCl

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

haloalkane to alcohol

A

substitution
KOH (aq) (reflux)
products = alcohol and potassium + halide

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

haloalkane to amine

A

substitution
NH3 (alc), warm
product = amine + hydrogen halide

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

amine to ammonium salt

A

neutralisation
acid (H+)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

alcohol to carboxylic acid

A

oxidation
MnO4-/H+ or Cr2O72-/H+ reflux
test for primary alcohol with Cr2O72- goes from orange to green as ions are reduced and dichromate doesn’t react with any other functional group
MnO4- goes from purple to colourless

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

carboxylic acid to carboxylate salt

A

neutralisation
base (OH-)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly