rates of reaction Flashcards
What are the four things the rate of a reaction depends on?
Temperature
Concentration ( or pressure for gases)
Catalyst
size of particles ( or surface area)
Why does a high surface area increase the rate of reaction?
Because there is a larger surface for the particles to collide with one another (or to collide with a catalyst) ,increasing the frequency of collisions and the likely hood of sucessful collisions.
Define collision theory
For a chemical reaction to occur, the reactant particles must collide and with enough energy for the collision to be succesful.
How does an increase in temperature affect the rate of reaction ?
It increases it because ff the particles have a higher temperature they have more and energy and so collide more often and are more likelly to have succesfull collisions.
How does a higher conc/ pressure affect the rate of reaction ?
If a solution is more concentrated it means there are more particles in the same volume so the frequency of collisions increases. Similarly, if a gas has a higher pressure then the particles are closer together.
why break up a solid reactant
if a solid reactant is broken up into pieces it’s surface area will increase, this means the particles around it in thr solution have more area to work on.
how do catalysts effect the rate of reaction?
a solid catalyst works by giving reacting particles a surface area to stick to. they increase the number of successful collisions by offering a reaction pathway with a lower activation energy.
describe a rates of reaction experiment that involves a change in mass
this works only for a reactions where a gas is given off. place you flask containing your solution on scales. As the gas is released the mass disappearing is easily measured on the scales. The quicker the reading on the balance drops the faster the rate of reaction.
equation for rate of reaction
rate of reaction = amount of reactant used or amount of product formed/ time
describe a rate of reaction experiment that involves a cloudy percipitate.
this is used when the product of the reaction forms a cloudy percipitate which clouds the solution. observe a marker throught the solution and see how long it takes to disappear. The quicker the marker disappears, the quicker the reaction.
how might out observe the effect of a catalyst on the rates of reaction?
meausure the rates of reaction for two solutions of exactly the same concentration, temperature and surface area of reactant, only one is reacted with a catalyst.
testing the effect of surface area
repeat identical experiments only with the reactant more crushed up each time. the finer the reactant is ground the faster the rate of reaction will be.
Describe an expriement for volume of gas given off.
This method uses a gas syringe to measure the volume of gas given off. The more gas given off during a given time interval, the faster the rate of reaction. Gas syringes are extremely accurate.
reaction of hydrochloric acid and marble chips - What it is often used for?
The effect of breaking up the solid reactant into smaller bits
How would you change the marble chips? what would you keep the same?
keep the mass of marble chips the same. Each time have it more crunched up.