Rates of reaction Flashcards
What is the rate of reaction
The rate of a chemical reaction is the speed with which reactants are converted into products
Collision theory - explain how it works
- For a chemical reaction to occur, the reactant molecules must collide with enough energy to break bonds
- The more collisions there are per unit of time, the faster the reaction will be
- The minimum kinetic energy required for a reaction to occur is called the activation energy (Ea).
- As the reactant molecules collide they must have enough energy to overcome the repulsive forces (Caused by outer electrons) and start to break the bonds between atoms
How to measure the rate of reaction?
- means measuring the change in amount of a reactant or the amount of a product
- the gradient of a graph is equal to the initial rate of reaction that that time
What is the rate of reaction determined by?
- The rate of a reaction is determined by the number of effective collisions per second
- As the reaction progresses, the concentration of reactants decreases
- This reduces the frequency of collisions between particles and so the reaction slows down
What are the factors that affect the rate of reaction, briefly explain
Temperature
Increase temperature = more energy (more force, move more quickly→more collisions) = reaction increase
Concentration
More concentration = more reactant moving (more collisions) = reaction increase
Particle size/surface area
Decrease particle size = increase surface are (more collisions) = faster reaction
Pressure
More pressure = smaller space (more collisions) = increase reaction
Catalyst
Are substances that change the rate of a reaction without being used up in the reaction
They never produce more product - they just produce the same amount more quickly
A catalyst can provide a surface for reactions to take place on.
Reactant molecules are held at a favourable angle for collisions to occur, increasing the likelihood of successful collisions.
Most of them lower the reaction’s activation energy
Stirring
As a chemical reaction proceeds, the particles of the reactants get used up. Hence, fewer collisions and the reaction slows down. Stirring helps the remaining reactants to collide.