rates Flashcards

1
Q

collision theory

A

reactant molecules must collide with sufficient energy and the correct orientation for a reaction to occur (bounce off otherwise)

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2
Q

area under curve for maxwell boltzmann distribution

A

of particles in sample

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3
Q

Ea

A

minimum amount of energy required for a reaction to occur

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4
Q

ROR key words

A

PER UNIT TIME

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5
Q

factors affecting ror: fq

A

surface area
concentration
pressure

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6
Q

factors affecting ror: proportion

A

temperature
catalyst

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7
Q

increase pressure with equal gas moles

A

bc equal gas moles, system cannot partially oppose therefore no effect on yield

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8
Q

increase temp favours higher ror bc

A

particles have more Ke tf collide with more force

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9
Q

when describing ror on graphs talk about

A

steepness of curves representing ror

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10
Q

improve accuracy of calculating ror by

A

measure pH
video record and stop video every certain time period

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11
Q

Kc represents

A

extent of reaction
> 10^4 reaction goes to completion
< 10^-4 reaction negligible extent only

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12
Q

equilibrium =

A

rate of forward and reverse reaction are equal

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13
Q

le chatellier principle key words

A

tendency to PARTIALLY OPPOSE change

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14
Q

what effect does adding inert gas have

A

NO EFFECT

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15
Q

what affects Kc

A

TEMPERATURE

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16
Q

How to determine theroretical voltage produced by a single cell

A

(NOT DEPENDENT ON BALANCING NUMBERS)
E(big) - E(small)

17
Q

what effects pH

A

ONLY H+ IONS (not OH)

18
Q

what effects neautrality/ making something acidic/basic

A

charge/ proportion of OH to H+

You can have a low pH hw the system still be neutral

19
Q

effect on temperture on Kc value

A

exothermic: as t increases -> k decreases
endothermic: as t increases -> k increases

20
Q

rate of reaction

A

change in concn of a reactant or pruduct per unit time

21
Q

catalysts

A

speed up chemical reactions, providing an alternative reaction pathway by lowing activation energy

22
Q

what does the equilibrium constant measure

A

the extent of the reaction

23
Q

what is the K value if the reaction goes to completion

A

K> 10 ^4

23
Q

what is the K value if reation occurs to a neglibible extent

A

K< 10^-4

24
Q

effect on Kc if equation is reversed

A

recipical of K

25
Q

effect on Kc if equation coefficients are doubled

A

K ^2

26
Q

effect on K if co-efficients are halved

A

K ^1/2

27
Q

effect on dilutions on equilibrium

A

dilution -> decrease concentration -> favour side with more aqu moles

hw this does not make solution more intense bc already diluted