Rates Flashcards
Collision Theory
In order for a reaction to occur:
- Reactant particles most collide
- with sufficient energy( greater than activation energy)
- and correct orientation
Maxwell- Boltzmann Distribution
Focus on the frequency of successful collisions
under curve= total number pf particles.
Activation Energy
The minimum amount of energy required for a reaction to take place.
Unit for reaction rate
M/s
Factors affecting rates of reaction
- Changing the surface area of solid reactions
- Changing the temperature of the reactants
- Changing the concentration of a solution
- Changing pressure of the reactant gases
- Using a catalyst
Surface Area
increasing the number of particles available to react
increasing the frequency of collisions
increasing the frequency of successful collisions
increasing rate of reaction
Increasing Temperature
- The average kinetic energy of particles is increased
- Greater propotion of particles having energy equal to or greater than the activation energy
- higher proportion of collisions being successful
- higher frequency of successful collisions
- rate of reaction increases.
Increasing concentration
- there is a higher number of particles per unit volume
- increase in collisions frequency
- greater frequency of successful collisions
- rate of reaction increases.
Catalysts
reduce the overall activation energy
increasing proportion of collisions that are successful
increasing frequency of successful collisions
increasing rate of reaction.
Pressure
increasing frequency of successful collisions bc more particles per unit volume
decrease in volume
increase in pressure
increase in volume
decrease in pressure
Dynamic equillibrium
a situation in which the rate of reaction of the forward and reverse reactions are equal, resulting in no observable changes overtime.
Maxwell-Boltzmann Distribution
a graph showing the distribution of energy across a sample of particles.
Reversible reaction
a chemical reaction that occurs in either the forward or reverse direction, given the appropriate conditions.