Rates Flashcards

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1
Q

Collision Theory

A

In order for a reaction to occur:

  • Reactant particles most collide
  • with sufficient energy( greater than activation energy)
  • and correct orientation
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2
Q

Maxwell- Boltzmann Distribution

A

Focus on the frequency of successful collisions

under curve= total number pf particles.

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3
Q

Activation Energy

A

The minimum amount of energy required for a reaction to take place.

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4
Q

Unit for reaction rate

A

M/s

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5
Q

Factors affecting rates of reaction

A
  • Changing the surface area of solid reactions
  • Changing the temperature of the reactants
  • Changing the concentration of a solution
  • Changing pressure of the reactant gases
  • Using a catalyst
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6
Q

Surface Area

A

increasing the number of particles available to react
increasing the frequency of collisions
increasing the frequency of successful collisions
increasing rate of reaction

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7
Q

Increasing Temperature

A
  • The average kinetic energy of particles is increased
  • Greater propotion of particles having energy equal to or greater than the activation energy
  • higher proportion of collisions being successful
  • higher frequency of successful collisions
  • rate of reaction increases.
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8
Q

Increasing concentration

A
  • there is a higher number of particles per unit volume
  • increase in collisions frequency
  • greater frequency of successful collisions
  • rate of reaction increases.
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9
Q

Catalysts

A

reduce the overall activation energy
increasing proportion of collisions that are successful
increasing frequency of successful collisions
increasing rate of reaction.

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10
Q

Pressure

A

increasing frequency of successful collisions bc more particles per unit volume

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11
Q

decrease in volume

A

increase in pressure

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12
Q

increase in volume

A

decrease in pressure

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13
Q

Dynamic equillibrium

A

a situation in which the rate of reaction of the forward and reverse reactions are equal, resulting in no observable changes overtime.

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14
Q

Maxwell-Boltzmann Distribution

A

a graph showing the distribution of energy across a sample of particles.

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15
Q

Reversible reaction

A

a chemical reaction that occurs in either the forward or reverse direction, given the appropriate conditions.

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16
Q

closed system

A

no substances can escape or be added.

17
Q

yeild

A

the amount of product produced.

18
Q

Le Chatelier’s principle

A

a system at equilibrium has a tendency to partially oppose disruption.

19
Q

Position of the equilibrium

A

an evaluation of the relative amount of products compared to reactants, at equilibrium

20
Q

Haber process

A
the industrial production of ammonia 
with:
- 400-450 degree temp
-200atm pressure
-iron catalyst 
-1:3 N:H