rate of reactions Flashcards
1st main method used to measure rate of reaction
how quickly reactants are used up or rate of disappearance of product
2nd main method used to measure rate of reaction
how quickly the product are formed or rate of appearance of product
formula
rate of reaction = amount of reactant used OR amount of product formed / time
common ways to measure rate of reaction experimentally
precipitation, change in mass, volume of gas given off
collision theory
- in a chemical reaction a collision is involved between reactant particles
- states that molecules must collide with sufficient energy (AE) and with suitable orientation to disrupt the bonds
collision theory applied to concentration
- if solution is more concentrated, there is greater density of reactant particles meaning there more collisions
- bc at the same proportion there is greater rate of collision
- greater rate of successful collisions
collision theory applied to subdivision
- by increasing surface area, we are exposing more of the reactant
- more reactant particles are available for collision
- higher successful collision rate
- faster reaction time
collision theory applied to temperature
1- reactant particles are moving faster meaning rate of collision increases
- increase of successful collision and faster reaction time
2- increasing temp effect molecular energies of reactants
- reactant have sufficient kinetic energy to supply AE needed for reaction
- successful collision and faster rate of reaction
catalyst
substance that speeds up a chemical reaction but is not used up in the reaction
collision theory applied to catalyst
- provides alternative pathway for the reaction than the one available with the reactant alone
- lower AE meaning less collision energy is required