Rate Of Reaction Flashcards
Collision theory
The collision theory states that the rate of a chemical reaction is directly proportional to the frequency of effective collisions.
Rate of reaction
The amount of products formed per unit time/ the amount of reactants used up per unit time
Change in Mass:
How will the mass of the content change over time?
[Gas ] will escape into the atmosphere, resulting in a loss of mass
Change in Mass:
How can the rate of reaction be calculated?
Plot a graph of mass of reaction mixture against time, gradient of the graph represent the rate of reaction at that point in time.
Measuring Change in Volume
Measure Volume of gas given off at regular time intervals using a gas syringe.
Factors affecting rate of reaction
Concentration, Pressure, Particle Size, Temperature, Presence of catalyst
Effect of concentration
When concentration of solution increases, the number of reactant particles per unit volume increases, increasing the frequency of effective collisions between the reactant particles, hence rate of reaction is faster.
Effect of pressure
As pressure of gas increases, reactant gas particles are forced closer, increasing the number of gaseous particles per unit volume, increasing the frequency of effective collision between the gaseous particles. Hence, the rate of reaction is faster.
Effect of Particle Size
As particle size decreases, there is a greater surface area for reacting particles to collide, increasing the frequency of effective collisions between the reactant particles. Hence, the rate of reaction is faster.
Effect of Temperature
As temperature increases, particles gain kinetic energy and move faster. As a result, there will be a higher proportion of particles having energy greater than or equal to activation energy, increasing the frequency of effective collisions between particles. Hence, the rate of reaction is faster.
Catalyst
A substance which increases the rate of a chemical reaction with itself remaining chemically unchanged at the end of the reaction.
Characteristics of a catalyst
- Changes the rate but not the yield of the chemical reaction
- Only a small amount is needed to change the rate of reaction.
- Not used up in the chemical reaction.
- Selective in its action. Different catalysts speed up specific chemical reactions.
Effect of a catalyst
A catalyst provides an alternative reaction pathway of lower activation energy,increases the proportion of particles having energy greater than or equals to the activation energy, increasing the frequency of effective collisions between the particles, hence rate of reaction is faster.
Use of catalyst
Iron- Ammonia
Platinum/ Rhodium- Catalytic converters
Aluminium oxide/ Silicone dioxide- production of hydrogen in cracking process
Enzymes
Biological catalyst that alter the rate of chemical reactions in plants and animals.