Rate Of Chemical Change Flashcards

1
Q

Mean rate of reaction=

A

Quantity of reactant used or product formed/ time taken

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2
Q

Units for rate of reaction

A

G/s or cm3/s

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3
Q

Rate of reaction depends on:

A

1) collision frequency
2) energy transferred during a collision
3) temperature
4) the presence of a catalyst
5) concentration of solution
6) pressure of gas
7) surface area

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4
Q

When you increase temperature…

A

Particles move faster, increasing collision frequency

The faster they move, the more energy they have to make the reaction

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5
Q

If solution is more concentrated…

A

There are more particles in the same volume of solution, increases collision frequency

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6
Q

If the pressure of gas is increased…

A

the same number of particles occupy a smaller space, increasing collision frequency

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7
Q

If one reactant is a solid, breaking it up into smaller pieces will…

A

Increase the surface area: volume ratio. This means that for the same volume of solid, particles around will have more area to work on

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8
Q

catalysts…

A

lower the activation energy needed for a reaction to take place by providing an alternative pathway

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9
Q

What are reversible reactions?

A

Chemical reactions where the products can react to produce the original reactants

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10
Q

The direction of reversible reactions can be changed by…

A

Changing the conditions

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11
Q

If a reversible reaction is exothermique in one direction…

A

Then it’s endothermic in the other

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12
Q

Equilibrium is reached when…

A

Forward and reverse reactions occur at exactly the same rate

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13
Q

Dynamic equilibrium?

A

If a reversible reaction is taking place in a closed system, d.e. happens when both forward and reverse reactions are taking place simultaneously and at the same rate of reaction

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14
Q

When equilibrium lies in the right…

A

conc. of products is greater than conc. of reactants

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15
Q

If equilibrium lies on the left…

A

The concentration of the reactants is greater than the products’

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16
Q

Position of equilibrium depends on:

A

1) temp
2) pressure (only affects equilibrium involving gases)
3) concentration of reactants and product(s)

17
Q

If a system is at equilibrium and a change is made to any of the conditions…

A

The system responds to counteract the change

18
Q

If conc of a reactant increased…

A

More products will be formed until equilibrium is reached again

19
Q

If conc of a product is decreased

A

More reactants will react until equilibrium is reached again

20
Q

If a temperature of a system at equilibrium is increased…

A

The relative amount of products INCREASES for an ENDOthermic reaction
The relative amount of products at equilibrium DECREASES for an EXOthermic reaction

21
Q

If a temperature of a system at an equilibrium is decreased…

A

The relative amount of products at equilibrium DECREASES for an ENDOthermic reaction
the relative amount of products at equilibrium INCREASES for an EXOthermic reaction

22
Q

For gaseous reaction at equilibrium…

A
  • an increase in pressure causes the equilibrium position to shift towards the side with a smaller number of molecules
  • a decreases in pressure causes the equilibrium position to shift towards the side with the larger number of molecules