Questiks Tesr Flashcards

1
Q

Defined the term first ionisation energy

A

The energy required to remove an electron from each atom in one mole of atoms in gaseous state

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2
Q

What is periodicity

A

Repeating pattern of properties across the periodic table

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3
Q

Write an equation for bleach

A

2NaOH + Cl2 —>NaClO + NaCl + H2O

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4
Q

A sample of Brine is a concentrated Aquarius solution of NaCl describe a simple chemical test that you could carry out to show the brine contains Aquarius chloride irons how would you confirm that no other halide ions are present include ionic equations in your answer

A

Add silver nitrate to cl- if a white precipitate is formed Cl- is present
Ag+ + cl- —> AgCl
Add dilute NH3 and if the precipitate completely dissolves

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5
Q

Group 2 elements also react with dilute hydrochloric acid describe and explain the trend in reactivity of the group 2 elements with dilute hydrochloric acid as the group is descended

A

Reactivity increases down the group as there is more shielding on the outer most electron has less nuclear attraction so it’s easier to remove the outermost electron so reactivity increases

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6
Q

Solid SIO2 melts at 2230°C solid SICL4 melt at -70° neither of the liquid form conducts electricity suggest the type of lattice structure in solid SIO2 and in solid SICL4 and explain the difference in Melting points in terms of bonding and structure

A

SIO2 is a giant covalent SICL4 is a simple molecule SICL4 has Vander walls forces and covalent bonds are broken in SIO2 forces are stronger in SIO2 so more energy is required to break forces mean in the boiling point is higher

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7
Q

Define relative atomic mass

A

The weighted mean mass of an atom relative to 1/12 of the mass of a carbon 12 atom

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8
Q

What is metallic bonding

A

metallic bond as (electrostatic) attraction between the electrons and the positive ions

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9
Q

Write the equation for the reaction of sodium with oxygen to form sodium oxide

A

4 Na + O2 —> 2 Na2O

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10
Q

What is ionic bonding

A

Electrostatic attraction between oppositely charged ions

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11
Q

Explain why the first ionisation energy sure a general increase from li to Ne

A

outer electrons closer to nucleus
nuclear charge increases
shielding remains the same

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12
Q

Explain the difference in first ionisation energies of LI and Na

A

atomic radii increase
there is more shielding
the nuclear attraction decreases

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13
Q

Write an equation to represent the second ionisation energy of oxygen including state symbols

A

O+(g) —> O2+(g + e–

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14
Q

Suggest why the second ionisation energy of oxygen has a greater value than the first ionisation energy

A

the electron repulsion/shielding is smaller

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15
Q

What is meant by the term atomic number

A

Number of protons in the nucleus

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16
Q

State the formula of the two ions are released when sulphuric acid is an Aquarius solution

A

H plus SO42 minus

17
Q

A student as a sample of solid potassium carbonate to an excess of dilute sulphuric acid describe what the student would see and write the equation for the reaction which place takes place

A

 Effervescence
potassium carbonate dissolve

H2SO4 + K2CO3 —> K2SO4 + CO2 + H2O

18
Q

What is meant by an orbital

A

A region of space that can hold up to 2 electrons

19
Q

What colour does Cl2 turn to when you add I- ions

A

Purple

20
Q

What colour does Br2 turn to when you add Cl- ions

A

Orange

21
Q

Eqquation for addition of CL2 to Br- ions

A

Cl2 +2Br– —> 2Cl– + Br2

22
Q

These three experiments alone are unable to confirm the order of reactivity for Chlorine bromine and iodine suggest one further displacement reaction which could be carried out to confirm the order of reactivity Of chlorine bromine and iodine

A

Addition of Br2(aq) to I–(aq) ions

23
Q

What is relative isotopic mass

A

The mass of an isotope compared to 1/12 of a carbon 12 atom

24
Q

Explain why xenon has a lower first ionisation energy than neon

A

Xenon has a bigger atomic radius
Xenon has more shielding
So the outermost electron has less nuclear attraction

25
Q

Predict the bond angle in a F2O molecule explain your answer

A

104

There are two bonded pairs and to lone pairs lone pairs repel more than bonded pairs

26
Q

A student has a solution that contains bromide ions the student carries out the following experiment step one Wilson chlorine gas through the sample of the solution the mixture changes colour write an ionic equation for the reaction that takes place in the step

A

Cl2 + 2Br- → Br2 + 2Cl–

27
Q

A student has a solution that contains bromide ions the student code of the following experiment step to the student then add an organic solvent cyclohexane to the mixture she shakes the content and allows the latest to separate what colour does the cyclohexane turning step to

A

Yellow

28
Q

Why does ICl have a higher boiling point than Cl2

A

ICl has more electrons. ORA
ALLOW I has more electrons ALLOW more van der Waals’ forces
Stronger van der Waals’ forces in ICl (than in Cl2) ORA OR
More energy is needed to overcome van der Waals’ forces in ICl ORA

29
Q

11
(b)
The hydrazine molecule, H,N-NH2, is covalent.
Predict the H-N-H bond angle in a hydrazine molecule.
Explain your answer.

A

Predicted bond angle 107o

There are 3 bonded pairs and 1 lone pair

Electron pairs repel
Lone pairs repel more than bonded pairs

30
Q

What is electronegativity

A

The ability of an atom to attract electrons in a covalent bond