Quantative Analysis Flashcards

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1
Q

What is the mass of 0.1 mole of sulfur dioxide.
(Oxygen = 16) (sulfur = 32)

A

16 x 2 = 32
32 + 32 = 64
64 x 0.1 = 6.4

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2
Q

What mass of magnesium oxide should be formed, (theoretical yield) when 2.4g of Mg reacts with 1.6g of O

A

2.4 + 1.6
4 grams

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3
Q

Calculate the percentage yield when theoretical yield is 4g and the theoretical yield is 3.3g.

A

3.3 ÷ 4 = 0.825
0.825 × 100 = 82.5

82.5%

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4
Q

What is the formula for atom economy?

A

Atom economy = (rfm of the useful product ÷ sum of rfm of all the reactants) ×100

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5
Q

What is the atom economy for making ammonia using nitrogen and hydrogen? N² + H⁶ = 2(NH³)

A

N² = 28
H⁶ = 6
NH³ = 17 17 × 2 = 34
Useful product equals 34
All reactants equal 34
34 ÷ 34 =1 1×100 = 100%

100%

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6
Q

How many moles are there in 66g of carbon dioxide. CO² C = 12 O = 16

A

12 + (16 ×2) = 44
66g ÷ 44 = 1.5 moles

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7
Q

What is the formula for concentration?

A

Mass of solute(g) ÷ volume of solution(dm³)
= concentration (g dm-3)

Dm is to the power of neg 3

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8
Q

25g of sulafte is dissolved in 500cm³ of water. What is the concentration in g dm-3

A

500 ÷ 1000 = 0.5 dm³
25 ÷ 0.5 = 50 gdm -3

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9
Q

What mass of sodium chloride is in 300cm³ of solution with a concentration of 12g dm-3?

A

300 ÷ 1000 = 0.3 dm³
12 × 0.3 = 3.6
3.6g of sodium chloride

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10
Q

What is avogadro’s constant?

A

6.02 x10²³

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11
Q

Calculate the number of moles in 90g of water. Rfm = 18

A

90 ÷ 18 = 5
5 moles

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12
Q

Calculate the mass of 0.200 moles of potassium bromide. Rfm of KBr = 119

A

119 x 0.2 = 23.8 moles

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13
Q

What mass of sodium hydroxide is contained in 200cm³ of a 55g dm-³ solution?

A

200 ÷ 1000 = 0.2 dm³
0.2 × 55 = 16.5
11g

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14
Q

What is the difference between chemical and empirical formulas?

A

Chemical formulas state the actual amount of atom of each element.
Empirical formulas state the smallest whole number ratio of the atoms

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15
Q

A sample of hydrocarbon contains 36g of carbon and 6g of hydrogen. Work out the empirical formula.
C = 12
H = 1

A

36g ÷ 12 = 3
3 moles of carbon
6 ÷ 1 = 6
6 moles of hydrogen
3 ÷ 3 = 1 Carbon
6 ÷ 3 = 2 Hydrogen
CH²

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16
Q

practical to find metal ions present

(flame test)

A

light Bunsen to blue flame (open air hole )

clean loop with HCl

pick small sample of test using loop

hold the loop with smample to edge of flame and observe colour

17
Q

how would u make the flame test more accurate
and how

A

by using a flame photomerty

.sensitivity- can detect smaller amounts
.accuracy-can give value closer to he true value
speed

18
Q

test for metal ions

what colour flame would you see for each ion present

A

lithium Li+ red
sodium Na+ yellow
potassium k+ lilac
calcium2+ Orange-red
copper2+ blue-green

19
Q

What is a mole?

A

1 mole is 6.02 x10²³ particles
1 moles of Oxygen gas(o²) weighs 32g
1 mole is also equal to the ram of a substance
To work out moles you do mass(g) divided by ram.
72 grams of oxygen gas would be 2 moles
72 grams of oxygen(O) would be 4 moles

20
Q

8.1g of zinc oxide reacts with 0.3g of carbon. The balanced chemical reaction is
2 ZnO + C -> CO² + 2 Zn

A

First work out moles.
Moles of zinc = 8.1 ÷ 81(ram) = 0.1 mol
Moles of Carbon = 0.3 ÷ 12 = 0.025 mol
The ratio of moles in terms of mass is 4 to 1. The ratio of moles needed for the reaction is 2 to 1. There is an excess amount of Zinc oxide.

Carbon is the limiting reactant

21
Q

how to work out concentration
using volume of solution (g dm3)

A

concentration (g dm3-) / volume of solution (dm-3)

22
Q

how to work out concentration with moles
(mol dm3-)

A

moles(mol)/ volume (dm3)

23
Q

how to work out concentration when given the mr of solute (mol dm3-)

A

conc/mr

24
Q

concentraion when given mass
(g dem-3)

A

mass/volume

25
Q

how to work out amount (mol)

A

volume (dm3) / molar volume (24)