Qualitative Tests Flashcards
How do you test for CO2?
Pass thru limewater
What is a pos result for CO2?
Colourless to milky
What indicates CO2 in XS?
Milky white ppt is sol and forms colourless solution
How do you test for H2? and Positive Result:
Burning splint into a sample of gas
Burns with a pop
How do you test for 02?
Put glowing splint into the sample of gas
Splint relights
How do you test for Cl2?
Damp litmus/ universal ind paper
Bleaches
How do you test for NH3?
Damp universal ind paper, then glass rod dipped in conc HCl acid.
Pos: turns blue and dense white flame
How do you test for HCl?
Damp universal indicator, glass rod dipped in conc NH3 sol
Pos: Turns reed and dense white flames
How do you dissolve a sol in h20?
Add a few spatula measures to a tt of deionised water and shake to mix
If it dissolves to form a col sol- Gr1/2/ammonium ion/ Zn/Al compound
How do you carry out a flame test?
Dip nichrome wire loop in conc Hcl acid, touch sample with wire, then hold it in Blue Bunsen flame
What is the colour of Li+?
Crimson
Na+
Yellow/orange
K+
Lilac
Ca2+
Brick Red
Ba2+
Green
Cu2+
Blue-Green
How do you test for the presence of halide ions?
Dissolve a spatula measure of solid sample in dilute HNO3 and add a few cm3 AgNO3 sol
Add dilute/ conc NH3 sol
What are the obs if Cl- present?
White ppt (AgCl) sol in both dilute and conc NH3 sol-> col. sol
What are the obs if Br- present?
Cream ppt (AgBr) - not sol. in dilute NH3 but sol in conc NH3 sol -> col. sol.
What are the obs if I- present?
Yellow ppt not sol. in either dilute/ conc NH3 sol.
How do you test for SO2-4 ions?
Dissolve spatula measure of s sample in dilute HNO3 acid (HCl acid also works) and add a few cm3 BaCl2
White ppt ( BaSO4) means present
How do you test for Carbonate Ions?
Place a few cm3 dilute acid in t.t and add a spatula measure of solid sample
What are the obs if CO2-3 ions are present?
Effervescence
S disappears
Gas evolved can be passed thru limewater in another t.t using a delivery tube
Limewater: colourless -> milky
How do you test for NH+4?
Place a few cm3 NaOH sol in tt and add spatula measure of a sample- warm gently
Test any gas evolved using damp red litmus paper/ glass rod dipped in conc HCl acid