Bonding Flashcards

1
Q

What particles are inv in ionic bonding?

A

Oppositely charged ions are held together by strong electrostatic forces of attr

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2
Q

Covalent Bonding

A

When non-metal atoms share e

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3
Q

What is the def of cov bond?

A

El. attr between a shared pair of e and the nuclei of bonded atoms

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4
Q

What is a lone pair?

A

Pair of e in outer shell of atom in a mol which is not being shared

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5
Q

What is a co-ord bond?

A

Shared pair of e with both e supplied by one atom

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6
Q

What is electronegativity?

A

Extent to which an atom attracts the bonding e in a cov bond

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6
Q

What is the Octet Rule?

A

When reacting, an atom tends to gain,lose or share e to achieve 8e in its outer shell

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7
Q

Why does EN increase as you go across period?

A

Nuclear charge increases
Shielding of shared pair constant
Shared pair is closer to nucleus

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8
Q

Why does EN increase as you go up group?

A

Shared pair closer to nucleus so is less shielded

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9
Q

What does polar mean?

A

When 2 atoms with dif EN held together by e. sharing bond

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10
Q

What is a dipole?

A

2 neighbouring partial (opposite) charges

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11
Q

What is metallic lattice?

A

Attr between pos ions and del e in a lattice

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12
Q

Why do metals have high bp?

A

B/c strong met bonds which are dif to break (a lot of en needed)

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13
Q

Why does mp increase from NA-MG-AL?

A

Positive ions have bigger charge and more delocalised e

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14
Q

Why are metals good e cond in s and l?

A

Del e are free to move and carry charge

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15
Q

What is ionic bonding?

A

The electrostatic attraction between oppositely charged ions in giant ionic lattice

16
Q

Why do ionic lattice have high mp?

A

Strong ionic bonds which are dif to break a lot of en needed

17
Q

Why does ionic lattice have poor ec in s state?

A

Ions are not free to move and carry charge

18
Q

Why are ions good e.c when molten/ aq?

A

Ions are free to move

19
Q

What is found in mol cov str?

A

Str cont small mol held together by IMF

20
Q

What is found between mol in mol cov str?

A

IM attr between mol- vdW attr

21
Q

What happens to iodine when heated? Why?

A

Sublimes to purple gas because weak attr overcome easily- v little en input needed

22
Q

Why are mol cov very poor e.c?

A

No del. e.

23
Q

What str does diamond have?

A

Giant Cov Str

24
What shape is diamond?
Tetrahedral arr around each C atom with strong cov bonds- RIGID and HARD- not brittle
25
Descr e.c of diamond?
No del e so very poor e.c
26
Descr mp of diamond:
Very high mp- strong cov bonds- dif to break- lots of en needed
27
What do diamond and graphite have in common?
Both allotropes of C- different forms of the same el in same phys state
28
Descr the bonding in graphite:
Attr between layers are weak- vdW attr Layers can easily slide over each other Within each layer, each C atom bonded to 3 others by cov bonds
29
What is the e.c of graphite?
Del can move and carry charge so good e.c
30
Descr the cov bonds in graphite:
Layers are strong and dif to break- subst en req- very high mp
31
What does each layer of graphite have?
Interlinking hex rings
32
Why does the strength of vdwf increase up halogens?
Size of mol increases More points of contact More vdwF
33
What is hydrogen bonding?
Mol which cont a H atom bonded to 1 of 3 most EN atoms (F,O,N) are attr to one another by H bonds