Bonding Flashcards

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1
Q

What particles are inv in ionic bonding?

A

Oppositely charged ions are held together by strong electrostatic forces of attr

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2
Q

Covalent Bonding

A

When non-metal atoms share e

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3
Q

What is the def of cov bond?

A

El. attr between a shared pair of e and the nuclei of bonded atoms

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4
Q

What is a lone pair?

A

Pair of e in outer shell of atom in a mol which is not being shared

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5
Q

What is a co-ord bond?

A

Shared pair of e with both e supplied by one atom

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6
Q

What is electronegativity?

A

Extent to which an atom attracts the bonding e in a cov bond

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6
Q

What is the Octet Rule?

A

When reacting, an atom tends to gain,lose or share e to achieve 8e in its outer shell

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7
Q

Why does EN increase as you go across period?

A

Nuclear charge increases
Shielding of shared pair constant
Shared pair is closer to nucleus

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8
Q

Why does EN increase as you go up group?

A

Shared pair closer to nucleus so is less shielded

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9
Q

What does polar mean?

A

When 2 atoms with dif EN held together by e. sharing bond

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10
Q

What is a dipole?

A

2 neighbouring partial (opposite) charges

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11
Q

What is metallic lattice?

A

Attr between pos ions and del e in a lattice

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12
Q

Why do metals have high bp?

A

B/c strong met bonds which are dif to break (a lot of en needed)

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13
Q

Why does mp increase from NA-MG-AL?

A

Positive ions have bigger charge and more delocalised e

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14
Q

Why are metals good e cond in s and l?

A

Del e are free to move and carry charge

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15
Q

What is ionic bonding?

A

The electrostatic attraction between oppositely charged ions in giant ionic lattice

16
Q

Why do ionic lattice have high mp?

A

Strong ionic bonds which are dif to break a lot of en needed

17
Q

Why does ionic lattice have poor ec in s state?

A

Ions are not free to move and carry charge

18
Q

Why are ions good e.c when molten/ aq?

A

Ions are free to move

19
Q

What is found in mol cov str?

A

Str cont small mol held together by IMF

20
Q

What is found between mol in mol cov str?

A

IM attr between mol- vdW attr

21
Q

What happens to iodine when heated? Why?

A

Sublimes to purple gas because weak attr overcome easily- v little en input needed

22
Q

Why are mol cov very poor e.c?

A

No del. e.

23
Q

What str does diamond have?

A

Giant Cov Str

24
Q

What shape is diamond?

A

Tetrahedral arr around each C atom with strong cov bonds- RIGID and HARD- not brittle

25
Q

Descr e.c of diamond?

A

No del e so very poor e.c

26
Q

Descr mp of diamond:

A

Very high mp- strong cov bonds- dif to break- lots of en needed

27
Q

What do diamond and graphite have in common?

A

Both allotropes of C- different forms of the same el in same phys state

28
Q

Descr the bonding in graphite:

A

Attr between layers are weak- vdW attr
Layers can easily slide over each other
Within each layer, each C atom bonded to 3 others by cov bonds

29
Q

What is the e.c of graphite?

A

Del can move and carry charge so good e.c

30
Q

Descr the cov bonds in graphite:

A

Layers are strong and dif to break- subst en req- very high mp

31
Q

What does each layer of graphite have?

A

Interlinking hex rings

32
Q

Why does the strength of vdwf increase up halogens?

A

Size of mol increases
More points of contact
More vdwF

33
Q

What is hydrogen bonding?

A

Mol which cont a H atom bonded to 1 of 3 most EN atoms (F,O,N) are attr to one another by H bonds